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2-Methyl-N-(3-methyl­phen­yl)benzamide

In the structure of the title compound (N3MP2MBA), C(15)H(15)NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti...

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Autores principales: Gowda, B. Thimme, Foro, Sabine, Sowmya, B. P., Fuess, Hartmut
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960197/
https://www.ncbi.nlm.nih.gov/pubmed/21201560
http://dx.doi.org/10.1107/S1600536808003103
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author Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_facet Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
author_sort Gowda, B. Thimme
collection PubMed
description In the structure of the title compound (N3MP2MBA), C(15)H(15)NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti to each other. The bond parameters in N3MP2MBA are similar to those in 2-methyl-N-phenyl­benzamide, N-(3,4-dimethyl­phen­yl)benzamide and other benzanilides. The amide group, –NHCO–, makes a dihedral angle of 55.2 (7)° with the benzoyl ring, while the dihedral angle between the two benzene rings (benzoyl and aniline) is 36.2 (1)°. N—H⋯O hydrogen bonds give rise to infinite chains running along the b axis of the crystal structure.
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spelling pubmed-29601972010-12-30 2-Methyl-N-(3-methyl­phen­yl)benzamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound (N3MP2MBA), C(15)H(15)NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti to each other. The bond parameters in N3MP2MBA are similar to those in 2-methyl-N-phenyl­benzamide, N-(3,4-dimethyl­phen­yl)benzamide and other benzanilides. The amide group, –NHCO–, makes a dihedral angle of 55.2 (7)° with the benzoyl ring, while the dihedral angle between the two benzene rings (benzoyl and aniline) is 36.2 (1)°. N—H⋯O hydrogen bonds give rise to infinite chains running along the b axis of the crystal structure. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960197/ /pubmed/21201560 http://dx.doi.org/10.1107/S1600536808003103 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gowda, B. Thimme
Foro, Sabine
Sowmya, B. P.
Fuess, Hartmut
2-Methyl-N-(3-methyl­phen­yl)benzamide
title 2-Methyl-N-(3-methyl­phen­yl)benzamide
title_full 2-Methyl-N-(3-methyl­phen­yl)benzamide
title_fullStr 2-Methyl-N-(3-methyl­phen­yl)benzamide
title_full_unstemmed 2-Methyl-N-(3-methyl­phen­yl)benzamide
title_short 2-Methyl-N-(3-methyl­phen­yl)benzamide
title_sort 2-methyl-n-(3-methyl­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960197/
https://www.ncbi.nlm.nih.gov/pubmed/21201560
http://dx.doi.org/10.1107/S1600536808003103
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