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2-Methyl-N-(3-methylphenyl)benzamide
In the structure of the title compound (N3MP2MBA), C(15)H(15)NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960197/ https://www.ncbi.nlm.nih.gov/pubmed/21201560 http://dx.doi.org/10.1107/S1600536808003103 |
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author | Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut |
author_facet | Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut |
author_sort | Gowda, B. Thimme |
collection | PubMed |
description | In the structure of the title compound (N3MP2MBA), C(15)H(15)NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti to each other. The bond parameters in N3MP2MBA are similar to those in 2-methyl-N-phenylbenzamide, N-(3,4-dimethylphenyl)benzamide and other benzanilides. The amide group, –NHCO–, makes a dihedral angle of 55.2 (7)° with the benzoyl ring, while the dihedral angle between the two benzene rings (benzoyl and aniline) is 36.2 (1)°. N—H⋯O hydrogen bonds give rise to infinite chains running along the b axis of the crystal structure. |
format | Text |
id | pubmed-2960197 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29601972010-12-30 2-Methyl-N-(3-methylphenyl)benzamide Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut Acta Crystallogr Sect E Struct Rep Online Organic Papers In the structure of the title compound (N3MP2MBA), C(15)H(15)NO, the conformation of the N—H bond is anti to the meta-methyl substituent in the aniline ring and that of the C=O bond is syn to the ortho-methyl substituent in the benzoyl ring, while the conformations of the N—H and C=O bonds are anti to each other. The bond parameters in N3MP2MBA are similar to those in 2-methyl-N-phenylbenzamide, N-(3,4-dimethylphenyl)benzamide and other benzanilides. The amide group, –NHCO–, makes a dihedral angle of 55.2 (7)° with the benzoyl ring, while the dihedral angle between the two benzene rings (benzoyl and aniline) is 36.2 (1)°. N—H⋯O hydrogen bonds give rise to infinite chains running along the b axis of the crystal structure. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960197/ /pubmed/21201560 http://dx.doi.org/10.1107/S1600536808003103 Text en © Gowda et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Gowda, B. Thimme Foro, Sabine Sowmya, B. P. Fuess, Hartmut 2-Methyl-N-(3-methylphenyl)benzamide |
title | 2-Methyl-N-(3-methylphenyl)benzamide |
title_full | 2-Methyl-N-(3-methylphenyl)benzamide |
title_fullStr | 2-Methyl-N-(3-methylphenyl)benzamide |
title_full_unstemmed | 2-Methyl-N-(3-methylphenyl)benzamide |
title_short | 2-Methyl-N-(3-methylphenyl)benzamide |
title_sort | 2-methyl-n-(3-methylphenyl)benzamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960197/ https://www.ncbi.nlm.nih.gov/pubmed/21201560 http://dx.doi.org/10.1107/S1600536808003103 |
work_keys_str_mv | AT gowdabthimme 2methyln3methylphenylbenzamide AT forosabine 2methyln3methylphenylbenzamide AT sowmyabp 2methyln3methylphenylbenzamide AT fuesshartmut 2methyln3methylphenylbenzamide |