trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate

In the title compound, [Cd(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(10)H(8)O(6)S(2)), the Cd(II) ion is located on a crystallographic inversion centre. An octa­hedral coordination geometry is defined by four water mol­ecules in one plane, and two trans N-atom donors of the nicotinamide ligands. The biphenyl-4...

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Detalles Bibliográficos
Autores principales: Li, Chunyuan, Chen, Min, Shao, Changlun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960200/
https://www.ncbi.nlm.nih.gov/pubmed/21201368
http://dx.doi.org/10.1107/S1600536808002390
Descripción
Sumario:In the title compound, [Cd(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(10)H(8)O(6)S(2)), the Cd(II) ion is located on a crystallographic inversion centre. An octa­hedral coordination geometry is defined by four water mol­ecules in one plane, and two trans N-atom donors of the nicotinamide ligands. The biphenyl-4,4′-disulfonate anion also lies on a crystallographic inversion centre. In the crystal structure, the complex cations are connected to the counter-anions via N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network.

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