trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate

In the title compound, [Cd(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(10)H(8)O(6)S(2)), the Cd(II) ion is located on a crystallographic inversion centre. An octa­hedral coordination geometry is defined by four water mol­ecules in one plane, and two trans N-atom donors of the nicotinamide ligands. The biphenyl-4...

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Detalles Bibliográficos
Autores principales: Li, Chunyuan, Chen, Min, Shao, Changlun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960200/
https://www.ncbi.nlm.nih.gov/pubmed/21201368
http://dx.doi.org/10.1107/S1600536808002390
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author Li, Chunyuan
Chen, Min
Shao, Changlun
author_facet Li, Chunyuan
Chen, Min
Shao, Changlun
author_sort Li, Chunyuan
collection PubMed
description In the title compound, [Cd(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(10)H(8)O(6)S(2)), the Cd(II) ion is located on a crystallographic inversion centre. An octa­hedral coordination geometry is defined by four water mol­ecules in one plane, and two trans N-atom donors of the nicotinamide ligands. The biphenyl-4,4′-disulfonate anion also lies on a crystallographic inversion centre. In the crystal structure, the complex cations are connected to the counter-anions via N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29602002010-12-30 trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate Li, Chunyuan Chen, Min Shao, Changlun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(C(6)H(6)N(2)O)(2)(H(2)O)(4)](C(10)H(8)O(6)S(2)), the Cd(II) ion is located on a crystallographic inversion centre. An octa­hedral coordination geometry is defined by four water mol­ecules in one plane, and two trans N-atom donors of the nicotinamide ligands. The biphenyl-4,4′-disulfonate anion also lies on a crystallographic inversion centre. In the crystal structure, the complex cations are connected to the counter-anions via N—H⋯O and O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2008-01-25 /pmc/articles/PMC2960200/ /pubmed/21201368 http://dx.doi.org/10.1107/S1600536808002390 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Chunyuan
Chen, Min
Shao, Changlun
trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate
title trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate
title_full trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate
title_fullStr trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate
title_full_unstemmed trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate
title_short trans-Tetra­aqua­bis(nicotinamide-κN)cadmium(II) biphenyl-4,4′-disulfonate
title_sort trans-tetra­aqua­bis(nicotinamide-κn)cadmium(ii) biphenyl-4,4′-disulfonate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960200/
https://www.ncbi.nlm.nih.gov/pubmed/21201368
http://dx.doi.org/10.1107/S1600536808002390
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AT chenmin transtetraaquabisnicotinamidekncadmiumiibiphenyl44disulfonate
AT shaochanglun transtetraaquabisnicotinamidekncadmiumiibiphenyl44disulfonate

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