Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride

There are independent cations and four chloride anions in the crystal structure of the title complex, [Co(C(6)H(6)N(4))(2)(H(2)O)(2)]Cl(2). In each cation, the Co(II) cation is coordinated by four N atoms from two biimidazole and two O atoms of two water mol­ecules; one Co atom is at a position of s...

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Detalles Bibliográficos
Autores principales: Zhang, Lan-Cui, Zhu, Zai-Ming, You, Wan-Sheng, Chang, Song, Wang, En-Bo
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960203/
https://www.ncbi.nlm.nih.gov/pubmed/21201281
http://dx.doi.org/10.1107/S160053680706833X
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author Zhang, Lan-Cui
Zhu, Zai-Ming
You, Wan-Sheng
Chang, Song
Wang, En-Bo
author_facet Zhang, Lan-Cui
Zhu, Zai-Ming
You, Wan-Sheng
Chang, Song
Wang, En-Bo
author_sort Zhang, Lan-Cui
collection PubMed
description There are independent cations and four chloride anions in the crystal structure of the title complex, [Co(C(6)H(6)N(4))(2)(H(2)O)(2)]Cl(2). In each cation, the Co(II) cation is coordinated by four N atoms from two biimidazole and two O atoms of two water mol­ecules; one Co atom is at a position of site symmetry m, the other at a position of site symmetry 2/m. All Cl(−) ions and water mol­ecules are also located on the mirror plane. Each structural unit is connected through O—H⋯Cl and N—H⋯Cl inter­molecular hydrogen bonds, forming a three–dimensional supramolecular structure.
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spelling pubmed-29602032010-12-30 Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride Zhang, Lan-Cui Zhu, Zai-Ming You, Wan-Sheng Chang, Song Wang, En-Bo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers There are independent cations and four chloride anions in the crystal structure of the title complex, [Co(C(6)H(6)N(4))(2)(H(2)O)(2)]Cl(2). In each cation, the Co(II) cation is coordinated by four N atoms from two biimidazole and two O atoms of two water mol­ecules; one Co atom is at a position of site symmetry m, the other at a position of site symmetry 2/m. All Cl(−) ions and water mol­ecules are also located on the mirror plane. Each structural unit is connected through O—H⋯Cl and N—H⋯Cl inter­molecular hydrogen bonds, forming a three–dimensional supramolecular structure. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960203/ /pubmed/21201281 http://dx.doi.org/10.1107/S160053680706833X Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhang, Lan-Cui
Zhu, Zai-Ming
You, Wan-Sheng
Chang, Song
Wang, En-Bo
Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride
title Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride
title_full Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride
title_fullStr Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride
title_full_unstemmed Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride
title_short Diaqua­bis(2,2′-biimidazole)cobalt(II) dichloride
title_sort diaqua­bis(2,2′-biimidazole)cobalt(ii) dichloride
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960203/
https://www.ncbi.nlm.nih.gov/pubmed/21201281
http://dx.doi.org/10.1107/S160053680706833X
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