Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K

In the title complex, [Zn(C(3)H(3)O(2))(C(27)H(27)N(7))](ClO(4))·C(3)H(7)NO·1.5CH(4)O, the Zn(II) ion is five-coordinated by four N atoms from a tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine (Mentb) ligand and one O atom from an acrylate ligand in a distorted trigonal–bipyramidal geometry with appro...

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Autores principales: Tian, Yongqiang, Wu, Huilu, Yun, Ruirui, Yuan, Jingkun, Ding, Jian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960207/
https://www.ncbi.nlm.nih.gov/pubmed/21201287
http://dx.doi.org/10.1107/S1600536807068675
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author Tian, Yongqiang
Wu, Huilu
Yun, Ruirui
Yuan, Jingkun
Ding, Jian
author_facet Tian, Yongqiang
Wu, Huilu
Yun, Ruirui
Yuan, Jingkun
Ding, Jian
author_sort Tian, Yongqiang
collection PubMed
description In the title complex, [Zn(C(3)H(3)O(2))(C(27)H(27)N(7))](ClO(4))·C(3)H(7)NO·1.5CH(4)O, the Zn(II) ion is five-coordinated by four N atoms from a tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine (Mentb) ligand and one O atom from an acrylate ligand in a distorted trigonal–bipyramidal geometry with approximate mol­ecular C (3) symmetry. The atoms of the acrylate ligand are disordered over two sites, with approximate occupancies of 0.84 and 0.16. In addition, a methanol solvent mol­ecule is disordered over two sites with equal occupancies. In the crystal structure, the full-occupancy methanol is linked to a dimethyl­formamide mol­ecule by an inter­molecular O—H⋯O hydrogen bond.
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spelling pubmed-29602072010-12-30 Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K Tian, Yongqiang Wu, Huilu Yun, Ruirui Yuan, Jingkun Ding, Jian Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Zn(C(3)H(3)O(2))(C(27)H(27)N(7))](ClO(4))·C(3)H(7)NO·1.5CH(4)O, the Zn(II) ion is five-coordinated by four N atoms from a tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine (Mentb) ligand and one O atom from an acrylate ligand in a distorted trigonal–bipyramidal geometry with approximate mol­ecular C (3) symmetry. The atoms of the acrylate ligand are disordered over two sites, with approximate occupancies of 0.84 and 0.16. In addition, a methanol solvent mol­ecule is disordered over two sites with equal occupancies. In the crystal structure, the full-occupancy methanol is linked to a dimethyl­formamide mol­ecule by an inter­molecular O—H⋯O hydrogen bond. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960207/ /pubmed/21201287 http://dx.doi.org/10.1107/S1600536807068675 Text en © Tian et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tian, Yongqiang
Wu, Huilu
Yun, Ruirui
Yuan, Jingkun
Ding, Jian
Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K
title Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K
title_full Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K
title_fullStr Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K
title_full_unstemmed Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K
title_short Acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(II) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) K
title_sort acrylato[tris­(1-methyl­benzimidazol-2-ylmeth­yl)amine]zinc(ii) perchlorate–dimethyl­formamide–methanol (1/1/1.5) at 153 (2) k
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960207/
https://www.ncbi.nlm.nih.gov/pubmed/21201287
http://dx.doi.org/10.1107/S1600536807068675
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