catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]

In the title compound, [Co(C(14)H(8)N(2)O(6))(H(2)O)(4)](n), each 5,5′-diazenediylbis(2-hydroxy­benzoato) ligand acts as a dicarboxyl­ate bridge, leading to the formation of polymeric chains running in the [[Image: see text]10] direction. The Co atom is hexa­coordinated in a distorted octa­hedral ge...

Descripción completa

Detalles Bibliográficos
Autores principales: Tan, Yu-Hui, Li, Yin-bao, Ji, Fa-Ming, Xiong, Ting-Ting, Xia, Li-Bin
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960221/
https://www.ncbi.nlm.nih.gov/pubmed/21201257
http://dx.doi.org/10.1107/S1600536807067827
_version_ 1782188687225782272
author Tan, Yu-Hui
Li, Yin-bao
Ji, Fa-Ming
Xiong, Ting-Ting
Xia, Li-Bin
author_facet Tan, Yu-Hui
Li, Yin-bao
Ji, Fa-Ming
Xiong, Ting-Ting
Xia, Li-Bin
author_sort Tan, Yu-Hui
collection PubMed
description In the title compound, [Co(C(14)H(8)N(2)O(6))(H(2)O)(4)](n), each 5,5′-diazenediylbis(2-hydroxy­benzoato) ligand acts as a dicarboxyl­ate bridge, leading to the formation of polymeric chains running in the [[Image: see text]10] direction. The Co atom is hexa­coordinated in a distorted octa­hedral geometry by six O atoms [Co—O = 2.039 (4)–2.115 (4) Å] from two ligands and four water mol­ecules. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds build up a three-dimensional supra­molecular structure.
format Text
id pubmed-2960221
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29602212010-12-30 catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato] Tan, Yu-Hui Li, Yin-bao Ji, Fa-Ming Xiong, Ting-Ting Xia, Li-Bin Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(14)H(8)N(2)O(6))(H(2)O)(4)](n), each 5,5′-diazenediylbis(2-hydroxy­benzoato) ligand acts as a dicarboxyl­ate bridge, leading to the formation of polymeric chains running in the [[Image: see text]10] direction. The Co atom is hexa­coordinated in a distorted octa­hedral geometry by six O atoms [Co—O = 2.039 (4)–2.115 (4) Å] from two ligands and four water mol­ecules. Inter­molecular O—H⋯O and O—H⋯N hydrogen bonds build up a three-dimensional supra­molecular structure. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960221/ /pubmed/21201257 http://dx.doi.org/10.1107/S1600536807067827 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Tan, Yu-Hui
Li, Yin-bao
Ji, Fa-Ming
Xiong, Ting-Ting
Xia, Li-Bin
catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]
title catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]
title_full catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]
title_fullStr catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]
title_full_unstemmed catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]
title_short catena-Poly[[tetra­aqua­cobalt(II)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]
title_sort catena-poly[[tetra­aqua­cobalt(ii)]-μ-2,2′-dihydroxy-5,5′-diazenediyldibenzoato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960221/
https://www.ncbi.nlm.nih.gov/pubmed/21201257
http://dx.doi.org/10.1107/S1600536807067827
work_keys_str_mv AT tanyuhui catenapolytetraaquacobaltiim22dihydroxy55diazenediyldibenzoato
AT liyinbao catenapolytetraaquacobaltiim22dihydroxy55diazenediyldibenzoato
AT jifaming catenapolytetraaquacobaltiim22dihydroxy55diazenediyldibenzoato
AT xiongtingting catenapolytetraaquacobaltiim22dihydroxy55diazenediyldibenzoato
AT xialibin catenapolytetraaquacobaltiim22dihydroxy55diazenediyldibenzoato

Ejemplares similares