Aqua­(3-hydroxy­benzoato-κO)bis­(1,10-phenanthroline-κ(2) N,N′)cobalt(II) 3-hydroxy­benzoate penta­hydrate

The crystal structure of the title compound, [Co(C(7)H(5)O(3))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(3))·5H(2)O, consists of Co(II) complex cations, uncoordinated hydroxy­benzoate anions and uncoord­inated water mol­ecules. The Co(II) ion is coordinated by two phenanthroline ligands, a water mol­ecule...

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Detalles Bibliográficos
Autores principales: Li, Jun-Hua, Nie, Jing-Jing, Su, Jian-Rong, Xu, Duan-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960224/
https://www.ncbi.nlm.nih.gov/pubmed/21201337
http://dx.doi.org/10.1107/S1600536808001815
Descripción
Sumario:The crystal structure of the title compound, [Co(C(7)H(5)O(3))(C(12)H(8)N(2))(2)(H(2)O)](C(7)H(5)O(3))·5H(2)O, consists of Co(II) complex cations, uncoordinated hydroxy­benzoate anions and uncoord­inated water mol­ecules. The Co(II) ion is coordinated by two phenanthroline ligands, a water mol­ecule and a 3-hydroxy­benzoate anion, and displays a distorted octa­hedral geometry. π–π stacking is observed between parallel phenanthroline ligands, the face-to-face separations being 3.454 (19) and 3.435 (7) Å. An extensive hydrogen-bonding network helps to stabilize the crystal structure. The hydroxybenzoate ligand is disordered over two positions, with site occupancy factors 0.6 and 0.4. One solvent water molecule is also disordered over two positions, with site occupancy factors 0.6 and 0.4.

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