Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate

In the title complex, [Cu(C(11)H(9)ClN(3)O(2))(2)]·4H(2)O, the Cu(II) atom is in a distorted octa­hedral coordination environment, coordinated by four N atoms and two O atoms from two tridentate 3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The mol­ecules are linked via inter­molecula...

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Detalles Bibliográficos
Autores principales: Zhao, Kai, Yin, Xian-Hong, Hu, Fei-Long, Lin, Cui-Wu, Zhang, Shang-Shang, Qing, Ru-Wen
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960233/
https://www.ncbi.nlm.nih.gov/pubmed/21201264
http://dx.doi.org/10.1107/S1600536807068110
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author Zhao, Kai
Yin, Xian-Hong
Hu, Fei-Long
Lin, Cui-Wu
Zhang, Shang-Shang
Qing, Ru-Wen
author_facet Zhao, Kai
Yin, Xian-Hong
Hu, Fei-Long
Lin, Cui-Wu
Zhang, Shang-Shang
Qing, Ru-Wen
author_sort Zhao, Kai
collection PubMed
description In the title complex, [Cu(C(11)H(9)ClN(3)O(2))(2)]·4H(2)O, the Cu(II) atom is in a distorted octa­hedral coordination environment, coordinated by four N atoms and two O atoms from two tridentate 3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The mol­ecules are linked via inter­molecular O—H⋯O hydrogen bonds involving water mol­ecules to form extended chains along [010], and there are short Cl⋯Cl contacts [3.153 (4) Å].
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spelling pubmed-29602332010-12-30 Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate Zhao, Kai Yin, Xian-Hong Hu, Fei-Long Lin, Cui-Wu Zhang, Shang-Shang Qing, Ru-Wen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(11)H(9)ClN(3)O(2))(2)]·4H(2)O, the Cu(II) atom is in a distorted octa­hedral coordination environment, coordinated by four N atoms and two O atoms from two tridentate 3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinate ligands. The mol­ecules are linked via inter­molecular O—H⋯O hydrogen bonds involving water mol­ecules to form extended chains along [010], and there are short Cl⋯Cl contacts [3.153 (4) Å]. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960233/ /pubmed/21201264 http://dx.doi.org/10.1107/S1600536807068110 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhao, Kai
Yin, Xian-Hong
Hu, Fei-Long
Lin, Cui-Wu
Zhang, Shang-Shang
Qing, Ru-Wen
Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate
title Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate
title_full Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate
title_fullStr Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate
title_full_unstemmed Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate
title_short Bis[3-chloro-6-(3,5-dimethyl-1H-pyrazol-1-yl)picolinato-κ(3) O,N,N′]copper(II) tetra­hydrate
title_sort bis[3-chloro-6-(3,5-dimethyl-1h-pyrazol-1-yl)picolinato-κ(3) o,n,n′]copper(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960233/
https://www.ncbi.nlm.nih.gov/pubmed/21201264
http://dx.doi.org/10.1107/S1600536807068110
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