Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)

In the title compound, [Cu(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)], the Cu atom adopts a square-based pyramidal CuN(4)O coordination, with the water O atom in the apical position. The pairs of N-bonded nicotinamide ligands and thio­cyanate anions in the basal plane are in a trans configuration. In the cry...

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Detalles Bibliográficos
Autores principales: Li, Chunyuan, Ding, Weijia, Shao, Changlun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960236/
https://www.ncbi.nlm.nih.gov/pubmed/21201285
http://dx.doi.org/10.1107/S1600536807068511
Descripción
Sumario:In the title compound, [Cu(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)], the Cu atom adopts a square-based pyramidal CuN(4)O coordination, with the water O atom in the apical position. The pairs of N-bonded nicotinamide ligands and thio­cyanate anions in the basal plane are in a trans configuration. In the crystal structure, the mol­ecules are connected into sheets by N—H⋯O and O—H⋯O hydrogen bonds.

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