Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)

In the title compound, [Cu(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)], the Cu atom adopts a square-based pyramidal CuN(4)O coordination, with the water O atom in the apical position. The pairs of N-bonded nicotinamide ligands and thio­cyanate anions in the basal plane are in a trans configuration. In the cry...

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Detalles Bibliográficos
Autores principales: Li, Chunyuan, Ding, Weijia, Shao, Changlun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960236/
https://www.ncbi.nlm.nih.gov/pubmed/21201285
http://dx.doi.org/10.1107/S1600536807068511
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author Li, Chunyuan
Ding, Weijia
Shao, Changlun
author_facet Li, Chunyuan
Ding, Weijia
Shao, Changlun
author_sort Li, Chunyuan
collection PubMed
description In the title compound, [Cu(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)], the Cu atom adopts a square-based pyramidal CuN(4)O coordination, with the water O atom in the apical position. The pairs of N-bonded nicotinamide ligands and thio­cyanate anions in the basal plane are in a trans configuration. In the crystal structure, the mol­ecules are connected into sheets by N—H⋯O and O—H⋯O hydrogen bonds.
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spelling pubmed-29602362010-12-30 Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II) Li, Chunyuan Ding, Weijia Shao, Changlun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(NCS)(2)(C(6)H(6)N(2)O)(2)(H(2)O)], the Cu atom adopts a square-based pyramidal CuN(4)O coordination, with the water O atom in the apical position. The pairs of N-bonded nicotinamide ligands and thio­cyanate anions in the basal plane are in a trans configuration. In the crystal structure, the mol­ecules are connected into sheets by N—H⋯O and O—H⋯O hydrogen bonds. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960236/ /pubmed/21201285 http://dx.doi.org/10.1107/S1600536807068511 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Chunyuan
Ding, Weijia
Shao, Changlun
Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)
title Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)
title_full Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)
title_fullStr Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)
title_full_unstemmed Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)
title_short Aqua­bis(nicotinamide-κN)(thio­cyanato-κN)copper(II)
title_sort aqua­bis(nicotinamide-κn)(thio­cyanato-κn)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960236/
https://www.ncbi.nlm.nih.gov/pubmed/21201285
http://dx.doi.org/10.1107/S1600536807068511
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AT dingweijia aquabisnicotinamideknthiocyanatokncopperii
AT shaochanglun aquabisnicotinamideknthiocyanatokncopperii

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