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Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate

The title complex, [Ag(2)(C(7)H(7)O(3)S)(2)(C(25)H(22)P(2))(2)]·H(2)O, was obtained by the reaction of silver toluene­sulfonate with diphenyl­phosphinomethane (dppm) in acetonitrile. There are two unique half-mol­ecules of the complex in the asymmetric unit, together with one water mol­ecule, which...

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Detalles Bibliográficos
Autores principales: Ma, Zhen, Sun, Jianhua, Liu, Baoqing, Hu, Miao, Xing, Yanpeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960244/
https://www.ncbi.nlm.nih.gov/pubmed/21201253
http://dx.doi.org/10.1107/S1600536807067311
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author Ma, Zhen
Sun, Jianhua
Liu, Baoqing
Hu, Miao
Xing, Yanpeng
author_facet Ma, Zhen
Sun, Jianhua
Liu, Baoqing
Hu, Miao
Xing, Yanpeng
author_sort Ma, Zhen
collection PubMed
description The title complex, [Ag(2)(C(7)H(7)O(3)S)(2)(C(25)H(22)P(2))(2)]·H(2)O, was obtained by the reaction of silver toluene­sulfonate with diphenyl­phosphinomethane (dppm) in acetonitrile. There are two unique half-mol­ecules of the complex in the asymmetric unit, together with one water mol­ecule, which is disordered over two positions with site occupancy factors of 0.6 and 0.4. In each centrosymmetric neutral dimeric mol­ecule, two Ag atoms are bridged by a pair of dppm ligands to give an eight-membered Ag(2)P(4)C(2) ring with a distorted AgOP(2) trigonal–planar environment. The Ag—Ag distances of 2.9215 (9) and 3.027 (1) Å indicate a direct bonding inter­action.
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spelling pubmed-29602442010-12-30 Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate Ma, Zhen Sun, Jianhua Liu, Baoqing Hu, Miao Xing, Yanpeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ag(2)(C(7)H(7)O(3)S)(2)(C(25)H(22)P(2))(2)]·H(2)O, was obtained by the reaction of silver toluene­sulfonate with diphenyl­phosphinomethane (dppm) in acetonitrile. There are two unique half-mol­ecules of the complex in the asymmetric unit, together with one water mol­ecule, which is disordered over two positions with site occupancy factors of 0.6 and 0.4. In each centrosymmetric neutral dimeric mol­ecule, two Ag atoms are bridged by a pair of dppm ligands to give an eight-membered Ag(2)P(4)C(2) ring with a distorted AgOP(2) trigonal–planar environment. The Ag—Ag distances of 2.9215 (9) and 3.027 (1) Å indicate a direct bonding inter­action. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960244/ /pubmed/21201253 http://dx.doi.org/10.1107/S1600536807067311 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Ma, Zhen
Sun, Jianhua
Liu, Baoqing
Hu, Miao
Xing, Yanpeng
Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate
title Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate
title_full Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate
title_fullStr Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate
title_full_unstemmed Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate
title_short Bis[μ-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(4-toluene­sulfonato-κO)silver(I)] monohydrate
title_sort bis[μ-bis­(diphenyl­phosphino)methane-κ(2) p:p′]bis­[(4-toluene­sulfonato-κo)silver(i)] monohydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960244/
https://www.ncbi.nlm.nih.gov/pubmed/21201253
http://dx.doi.org/10.1107/S1600536807067311
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