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Bis[μ-bis(diphenylphosphino)methane-κ(2) P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate
The title complex, [Ag(2)(C(7)H(7)O(3)S)(2)(C(25)H(22)P(2))(2)]·H(2)O, was obtained by the reaction of silver toluenesulfonate with diphenylphosphinomethane (dppm) in acetonitrile. There are two unique half-molecules of the complex in the asymmetric unit, together with one water molecule, which...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960244/ https://www.ncbi.nlm.nih.gov/pubmed/21201253 http://dx.doi.org/10.1107/S1600536807067311 |
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author | Ma, Zhen Sun, Jianhua Liu, Baoqing Hu, Miao Xing, Yanpeng |
author_facet | Ma, Zhen Sun, Jianhua Liu, Baoqing Hu, Miao Xing, Yanpeng |
author_sort | Ma, Zhen |
collection | PubMed |
description | The title complex, [Ag(2)(C(7)H(7)O(3)S)(2)(C(25)H(22)P(2))(2)]·H(2)O, was obtained by the reaction of silver toluenesulfonate with diphenylphosphinomethane (dppm) in acetonitrile. There are two unique half-molecules of the complex in the asymmetric unit, together with one water molecule, which is disordered over two positions with site occupancy factors of 0.6 and 0.4. In each centrosymmetric neutral dimeric molecule, two Ag atoms are bridged by a pair of dppm ligands to give an eight-membered Ag(2)P(4)C(2) ring with a distorted AgOP(2) trigonal–planar environment. The Ag—Ag distances of 2.9215 (9) and 3.027 (1) Å indicate a direct bonding interaction. |
format | Text |
id | pubmed-2960244 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29602442010-12-30 Bis[μ-bis(diphenylphosphino)methane-κ(2) P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate Ma, Zhen Sun, Jianhua Liu, Baoqing Hu, Miao Xing, Yanpeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ag(2)(C(7)H(7)O(3)S)(2)(C(25)H(22)P(2))(2)]·H(2)O, was obtained by the reaction of silver toluenesulfonate with diphenylphosphinomethane (dppm) in acetonitrile. There are two unique half-molecules of the complex in the asymmetric unit, together with one water molecule, which is disordered over two positions with site occupancy factors of 0.6 and 0.4. In each centrosymmetric neutral dimeric molecule, two Ag atoms are bridged by a pair of dppm ligands to give an eight-membered Ag(2)P(4)C(2) ring with a distorted AgOP(2) trigonal–planar environment. The Ag—Ag distances of 2.9215 (9) and 3.027 (1) Å indicate a direct bonding interaction. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960244/ /pubmed/21201253 http://dx.doi.org/10.1107/S1600536807067311 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Ma, Zhen Sun, Jianhua Liu, Baoqing Hu, Miao Xing, Yanpeng Bis[μ-bis(diphenylphosphino)methane-κ(2) P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate |
title | Bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate |
title_full | Bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate |
title_fullStr | Bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate |
title_full_unstemmed | Bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate |
title_short | Bis[μ-bis(diphenylphosphino)methane-κ(2)
P:P′]bis[(4-toluenesulfonato-κO)silver(I)] monohydrate |
title_sort | bis[μ-bis(diphenylphosphino)methane-κ(2)
p:p′]bis[(4-toluenesulfonato-κo)silver(i)] monohydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960244/ https://www.ncbi.nlm.nih.gov/pubmed/21201253 http://dx.doi.org/10.1107/S1600536807067311 |
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