Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]

In the title compound, {[Mn(C(4)H(4)O(6))(H(2)O)]·H(2)O}(n), the Mn(2+) ion is connected to three different tartrate anions and a water mol­ecule, resulting in a distorted MnO(6) octa­hedral geometry. There are two tartrate half-anions in the asymmetric unit, both of which are completed by crystallo...

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Detalles Bibliográficos
Autores principales: Ge, Chunhua, Zhao, Zhen, Han, Guangxi, Zhang, Xiangdong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960245/
https://www.ncbi.nlm.nih.gov/pubmed/21201319
http://dx.doi.org/10.1107/S1600536807067839
Descripción
Sumario:In the title compound, {[Mn(C(4)H(4)O(6))(H(2)O)]·H(2)O}(n), the Mn(2+) ion is connected to three different tartrate anions and a water mol­ecule, resulting in a distorted MnO(6) octa­hedral geometry. There are two tartrate half-anions in the asymmetric unit, both of which are completed by crystallographic twofold rotation symmetry. The tartrate dianions bridge the Mn(2+) ions to form a wave-like infinite layer. A series of O—H⋯O hydrogen bonds link the layers into a three-dimensional network.

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