Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]

In the title compound, {[Mn(C(4)H(4)O(6))(H(2)O)]·H(2)O}(n), the Mn(2+) ion is connected to three different tartrate anions and a water mol­ecule, resulting in a distorted MnO(6) octa­hedral geometry. There are two tartrate half-anions in the asymmetric unit, both of which are completed by crystallo...

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Detalles Bibliográficos
Autores principales: Ge, Chunhua, Zhao, Zhen, Han, Guangxi, Zhang, Xiangdong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960245/
https://www.ncbi.nlm.nih.gov/pubmed/21201319
http://dx.doi.org/10.1107/S1600536807067839
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author Ge, Chunhua
Zhao, Zhen
Han, Guangxi
Zhang, Xiangdong
author_facet Ge, Chunhua
Zhao, Zhen
Han, Guangxi
Zhang, Xiangdong
author_sort Ge, Chunhua
collection PubMed
description In the title compound, {[Mn(C(4)H(4)O(6))(H(2)O)]·H(2)O}(n), the Mn(2+) ion is connected to three different tartrate anions and a water mol­ecule, resulting in a distorted MnO(6) octa­hedral geometry. There are two tartrate half-anions in the asymmetric unit, both of which are completed by crystallographic twofold rotation symmetry. The tartrate dianions bridge the Mn(2+) ions to form a wave-like infinite layer. A series of O—H⋯O hydrogen bonds link the layers into a three-dimensional network.
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spelling pubmed-29602452010-12-30 Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate] Ge, Chunhua Zhao, Zhen Han, Guangxi Zhang, Xiangdong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Mn(C(4)H(4)O(6))(H(2)O)]·H(2)O}(n), the Mn(2+) ion is connected to three different tartrate anions and a water mol­ecule, resulting in a distorted MnO(6) octa­hedral geometry. There are two tartrate half-anions in the asymmetric unit, both of which are completed by crystallographic twofold rotation symmetry. The tartrate dianions bridge the Mn(2+) ions to form a wave-like infinite layer. A series of O—H⋯O hydrogen bonds link the layers into a three-dimensional network. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960245/ /pubmed/21201319 http://dx.doi.org/10.1107/S1600536807067839 Text en © Ge et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ge, Chunhua
Zhao, Zhen
Han, Guangxi
Zhang, Xiangdong
Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]
title Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]
title_full Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]
title_fullStr Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]
title_full_unstemmed Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]
title_short Poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(II)] dihydrate]
title_sort poly[[diaqua-μ(4)-tartrato-μ(2)-tartrato-dimanganese(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960245/
https://www.ncbi.nlm.nih.gov/pubmed/21201319
http://dx.doi.org/10.1107/S1600536807067839
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AT zhangxiangdong polydiaquam4tartratom2tartratodimanganeseiidihydrate

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