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Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate

The title compound, {systematic name: (3-carb­oxy-1-ethyl-6-fluoro-7-piperazin-4-ium-1-yl-1H-quinolin-4-yl­idene)oxonium tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate], (C(16)H(20)FN(3)O(3))(2)[Bi(2)Cl(9)]Cl·2H(2)O, is composed of [Bi(2)Cl(9)](3−) anions lying on crystallogra...

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Detalles Bibliográficos
Autores principales: Gerasimenko, A. V., Karaseva, E. T., Polishchuk, A. V.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960246/
https://www.ncbi.nlm.nih.gov/pubmed/21201333
http://dx.doi.org/10.1107/S1600536808001244
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author Gerasimenko, A. V.
Karaseva, E. T.
Polishchuk, A. V.
author_facet Gerasimenko, A. V.
Karaseva, E. T.
Polishchuk, A. V.
author_sort Gerasimenko, A. V.
collection PubMed
description The title compound, {systematic name: (3-carb­oxy-1-ethyl-6-fluoro-7-piperazin-4-ium-1-yl-1H-quinolin-4-yl­idene)oxonium tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate], (C(16)H(20)FN(3)O(3))(2)[Bi(2)Cl(9)]Cl·2H(2)O, is composed of [Bi(2)Cl(9)](3−) anions lying on crystallographic twofold rotation axes, Cl(−) anions also on twofold axes, C(16)H(20)FN(3)O(3) (2+) cations, and water mol­ecules. The Bi(III) coordination polyhedron is a distorted octa­hedron and two such octa­hedra share a triangular face to form the complex anion. There are three short terminal Bi—Cl bonds [2.5471 (6)–2.5781(5 Å] and three longer bridging bonds [2.8599 (5)–2.9984 (6) Å] in each octa­hedron. Anions, cations and water mol­ecules are linked by hydrogen bonds to form a three-dimensional network. There are also π–π stacking inter­actions between quinoline ring systems, with an inter­planar distance of 3.27 (1) Å.
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spelling pubmed-29602462010-12-30 Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate Gerasimenko, A. V. Karaseva, E. T. Polishchuk, A. V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {systematic name: (3-carb­oxy-1-ethyl-6-fluoro-7-piperazin-4-ium-1-yl-1H-quinolin-4-yl­idene)oxonium tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate], (C(16)H(20)FN(3)O(3))(2)[Bi(2)Cl(9)]Cl·2H(2)O, is composed of [Bi(2)Cl(9)](3−) anions lying on crystallographic twofold rotation axes, Cl(−) anions also on twofold axes, C(16)H(20)FN(3)O(3) (2+) cations, and water mol­ecules. The Bi(III) coordination polyhedron is a distorted octa­hedron and two such octa­hedra share a triangular face to form the complex anion. There are three short terminal Bi—Cl bonds [2.5471 (6)–2.5781(5 Å] and three longer bridging bonds [2.8599 (5)–2.9984 (6) Å] in each octa­hedron. Anions, cations and water mol­ecules are linked by hydrogen bonds to form a three-dimensional network. There are also π–π stacking inter­actions between quinoline ring systems, with an inter­planar distance of 3.27 (1) Å. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960246/ /pubmed/21201333 http://dx.doi.org/10.1107/S1600536808001244 Text en © Gerasimenko et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gerasimenko, A. V.
Karaseva, E. T.
Polishchuk, A. V.
Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate
title Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate
title_full Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate
title_fullStr Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate
title_full_unstemmed Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate
title_short Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(III)] chloride dihydrate
title_sort bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis­[trichloridobismuthate(iii)] chloride dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960246/
https://www.ncbi.nlm.nih.gov/pubmed/21201333
http://dx.doi.org/10.1107/S1600536808001244
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AT karasevaet bisdihydrogennorfloxaciniumtrim2chloridobistrichloridobismuthateiiichloridedihydrate
AT polishchukav bisdihydrogennorfloxaciniumtrim2chloridobistrichloridobismuthateiiichloridedihydrate