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Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate
The title compound, {systematic name: (3-carboxy-1-ethyl-6-fluoro-7-piperazin-4-ium-1-yl-1H-quinolin-4-ylidene)oxonium tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate], (C(16)H(20)FN(3)O(3))(2)[Bi(2)Cl(9)]Cl·2H(2)O, is composed of [Bi(2)Cl(9)](3−) anions lying on crystallogra...
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960246/ https://www.ncbi.nlm.nih.gov/pubmed/21201333 http://dx.doi.org/10.1107/S1600536808001244 |
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author | Gerasimenko, A. V. Karaseva, E. T. Polishchuk, A. V. |
author_facet | Gerasimenko, A. V. Karaseva, E. T. Polishchuk, A. V. |
author_sort | Gerasimenko, A. V. |
collection | PubMed |
description | The title compound, {systematic name: (3-carboxy-1-ethyl-6-fluoro-7-piperazin-4-ium-1-yl-1H-quinolin-4-ylidene)oxonium tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate], (C(16)H(20)FN(3)O(3))(2)[Bi(2)Cl(9)]Cl·2H(2)O, is composed of [Bi(2)Cl(9)](3−) anions lying on crystallographic twofold rotation axes, Cl(−) anions also on twofold axes, C(16)H(20)FN(3)O(3) (2+) cations, and water molecules. The Bi(III) coordination polyhedron is a distorted octahedron and two such octahedra share a triangular face to form the complex anion. There are three short terminal Bi—Cl bonds [2.5471 (6)–2.5781(5 Å] and three longer bridging bonds [2.8599 (5)–2.9984 (6) Å] in each octahedron. Anions, cations and water molecules are linked by hydrogen bonds to form a three-dimensional network. There are also π–π stacking interactions between quinoline ring systems, with an interplanar distance of 3.27 (1) Å. |
format | Text |
id | pubmed-2960246 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29602462010-12-30 Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate Gerasimenko, A. V. Karaseva, E. T. Polishchuk, A. V. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, {systematic name: (3-carboxy-1-ethyl-6-fluoro-7-piperazin-4-ium-1-yl-1H-quinolin-4-ylidene)oxonium tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate], (C(16)H(20)FN(3)O(3))(2)[Bi(2)Cl(9)]Cl·2H(2)O, is composed of [Bi(2)Cl(9)](3−) anions lying on crystallographic twofold rotation axes, Cl(−) anions also on twofold axes, C(16)H(20)FN(3)O(3) (2+) cations, and water molecules. The Bi(III) coordination polyhedron is a distorted octahedron and two such octahedra share a triangular face to form the complex anion. There are three short terminal Bi—Cl bonds [2.5471 (6)–2.5781(5 Å] and three longer bridging bonds [2.8599 (5)–2.9984 (6) Å] in each octahedron. Anions, cations and water molecules are linked by hydrogen bonds to form a three-dimensional network. There are also π–π stacking interactions between quinoline ring systems, with an interplanar distance of 3.27 (1) Å. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960246/ /pubmed/21201333 http://dx.doi.org/10.1107/S1600536808001244 Text en © Gerasimenko et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Gerasimenko, A. V. Karaseva, E. T. Polishchuk, A. V. Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate |
title | Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate |
title_full | Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate |
title_fullStr | Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate |
title_full_unstemmed | Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate |
title_short | Bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(III)] chloride dihydrate |
title_sort | bis(dihydrogen norfloxacinium) tri-μ(2)-chlorido-bis[trichloridobismuthate(iii)] chloride dihydrate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960246/ https://www.ncbi.nlm.nih.gov/pubmed/21201333 http://dx.doi.org/10.1107/S1600536808001244 |
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