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Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)

Each Cu atom in the dinuclear centrosymmetric title complex, [Cu(2)Br(2)(C(14)H(17)N(3))(2)](ClO(4))(2), is ligated in a distorted square-pyramidal geometry (τ = 0.31) by a tridentate bis­[2-(2-pyrid­yl)eth­yl]amine ligand, and by two bridging Br atoms. In addition, the dinuclear species is stabiliz...

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Detalles Bibliográficos
Autores principales: Butcher, Ray J., Gultneh, Yilma, Yisgedu, Teshome B., Tesema, Yohannes T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960247/
https://www.ncbi.nlm.nih.gov/pubmed/21201292
http://dx.doi.org/10.1107/S1600536807068663
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author Butcher, Ray J.
Gultneh, Yilma
Yisgedu, Teshome B.
Tesema, Yohannes T.
author_facet Butcher, Ray J.
Gultneh, Yilma
Yisgedu, Teshome B.
Tesema, Yohannes T.
author_sort Butcher, Ray J.
collection PubMed
description Each Cu atom in the dinuclear centrosymmetric title complex, [Cu(2)Br(2)(C(14)H(17)N(3))(2)](ClO(4))(2), is ligated in a distorted square-pyramidal geometry (τ = 0.31) by a tridentate bis­[2-(2-pyrid­yl)eth­yl]amine ligand, and by two bridging Br atoms. In addition, the dinuclear species is stabilized by two hydrogen-bonded perchlorate anions.
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spelling pubmed-29602472010-12-30 Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate) Butcher, Ray J. Gultneh, Yilma Yisgedu, Teshome B. Tesema, Yohannes T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Each Cu atom in the dinuclear centrosymmetric title complex, [Cu(2)Br(2)(C(14)H(17)N(3))(2)](ClO(4))(2), is ligated in a distorted square-pyramidal geometry (τ = 0.31) by a tridentate bis­[2-(2-pyrid­yl)eth­yl]amine ligand, and by two bridging Br atoms. In addition, the dinuclear species is stabilized by two hydrogen-bonded perchlorate anions. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960247/ /pubmed/21201292 http://dx.doi.org/10.1107/S1600536807068663 Text en © Butcher et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Butcher, Ray J.
Gultneh, Yilma
Yisgedu, Teshome B.
Tesema, Yohannes T.
Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)
title Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)
title_full Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)
title_fullStr Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)
title_full_unstemmed Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)
title_short Di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(II)) bis­(perchlorate)
title_sort di-μ-bromido-bis­({bis­[2-(2-pyrid­yl)eth­yl]amine}copper(ii)) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960247/
https://www.ncbi.nlm.nih.gov/pubmed/21201292
http://dx.doi.org/10.1107/S1600536807068663
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