4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione

In the title compound, C(10)H(9)BrN(4)OS, the triazole ring forms a dihedral angle of 72.05 (14)° with the benzene ring. The conformation of the mol­ecule is stabilized by intra­molecular O—H⋯·N hydrogen bonding. The crystal packing is determined by inter­molecular N—H⋯S inter­actions, a short Br⋯S...

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Detalles Bibliográficos
Autores principales: Wang, Min, Cao, Minna, Hu, Bo, Cheng, CuiXia, Song, XueGang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960248/
https://www.ncbi.nlm.nih.gov/pubmed/21201405
http://dx.doi.org/10.1107/S1600536807062149
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author Wang, Min
Cao, Minna
Hu, Bo
Cheng, CuiXia
Song, XueGang
author_facet Wang, Min
Cao, Minna
Hu, Bo
Cheng, CuiXia
Song, XueGang
author_sort Wang, Min
collection PubMed
description In the title compound, C(10)H(9)BrN(4)OS, the triazole ring forms a dihedral angle of 72.05 (14)° with the benzene ring. The conformation of the mol­ecule is stabilized by intra­molecular O—H⋯·N hydrogen bonding. The crystal packing is determined by inter­molecular N—H⋯S inter­actions, a short Br⋯S contact of 3.4464 (13) Å and π–π stacking of the triazole rings and of the benzene rings (centroid–centroid distances of 3.4109 and 3.569 Å, respectively).
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spelling pubmed-29602482010-12-30 4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione Wang, Min Cao, Minna Hu, Bo Cheng, CuiXia Song, XueGang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(9)BrN(4)OS, the triazole ring forms a dihedral angle of 72.05 (14)° with the benzene ring. The conformation of the mol­ecule is stabilized by intra­molecular O—H⋯·N hydrogen bonding. The crystal packing is determined by inter­molecular N—H⋯S inter­actions, a short Br⋯S contact of 3.4464 (13) Å and π–π stacking of the triazole rings and of the benzene rings (centroid–centroid distances of 3.4109 and 3.569 Å, respectively). International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960248/ /pubmed/21201405 http://dx.doi.org/10.1107/S1600536807062149 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Wang, Min
Cao, Minna
Hu, Bo
Cheng, CuiXia
Song, XueGang
4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title 4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_full 4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_fullStr 4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_full_unstemmed 4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_short 4-(5-Bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1H-1,2,4-triazole-5(4H)-thione
title_sort 4-(5-bromo-2-hydroxy­benzyl­idene­amino)-3-methyl-1h-1,2,4-triazole-5(4h)-thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960248/
https://www.ncbi.nlm.nih.gov/pubmed/21201405
http://dx.doi.org/10.1107/S1600536807062149
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AT chengcuixia 45bromo2hydroxybenzylideneamino3methyl1h124triazole54hthione
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