Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]

In the title coordination polymer, {[BaCu(2)(C(9)H(4)NO(5))(2)(C(3)H(4)N(2))(2)(H(2)O)(4)]·2H(2)O}(n), the Ba(2+) cation is deca­coordinate, ligated by four aqua ligands and four [Cu(C(9)H(4)O(5)N)(C(3)H(4)N(2))] ‘complex ligands’. The Cu(II)-containing complex-ligands are bridged by the Ba(2+) cati...

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Detalles Bibliográficos
Autores principales: Mei, Chongzhen, Li, Kaihui, Zhang, Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960249/
https://www.ncbi.nlm.nih.gov/pubmed/21201315
http://dx.doi.org/10.1107/S1600536808000597
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author Mei, Chongzhen
Li, Kaihui
Zhang, Peng
author_facet Mei, Chongzhen
Li, Kaihui
Zhang, Peng
author_sort Mei, Chongzhen
collection PubMed
description In the title coordination polymer, {[BaCu(2)(C(9)H(4)NO(5))(2)(C(3)H(4)N(2))(2)(H(2)O)(4)]·2H(2)O}(n), the Ba(2+) cation is deca­coordinate, ligated by four aqua ligands and four [Cu(C(9)H(4)O(5)N)(C(3)H(4)N(2))] ‘complex ligands’. The Cu(II)-containing complex-ligands are bridged by the Ba(2+) cations, resulting in a one-dimensional polymeric chain structure. The crystal structure is maintained via N—H⋯O and O—H⋯O hydrogen bonds. There is one disordered solvent water mol­ecule in the asymmetric unit, with occupancies of 0.44 (2) and 0.56 (2).
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spelling pubmed-29602492010-12-30 Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate] Mei, Chongzhen Li, Kaihui Zhang, Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[BaCu(2)(C(9)H(4)NO(5))(2)(C(3)H(4)N(2))(2)(H(2)O)(4)]·2H(2)O}(n), the Ba(2+) cation is deca­coordinate, ligated by four aqua ligands and four [Cu(C(9)H(4)O(5)N)(C(3)H(4)N(2))] ‘complex ligands’. The Cu(II)-containing complex-ligands are bridged by the Ba(2+) cations, resulting in a one-dimensional polymeric chain structure. The crystal structure is maintained via N—H⋯O and O—H⋯O hydrogen bonds. There is one disordered solvent water mol­ecule in the asymmetric unit, with occupancies of 0.44 (2) and 0.56 (2). International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960249/ /pubmed/21201315 http://dx.doi.org/10.1107/S1600536808000597 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Mei, Chongzhen
Li, Kaihui
Zhang, Peng
Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_full Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_fullStr Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_full_unstemmed Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_short Poly[[tetra­aqua­bis(1H-imidazole-κN (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(II)barium(II)] dihydrate]
title_sort poly[[tetra­aqua­bis(1h-imidazole-κn (3))bis­[2-(oxaloamino)benzoato(3–)]dicopper(ii)barium(ii)] dihydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960249/
https://www.ncbi.nlm.nih.gov/pubmed/21201315
http://dx.doi.org/10.1107/S1600536808000597
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AT likaihui polytetraaquabis1himidazolekn3bis2oxaloaminobenzoato3dicopperiibariumiidihydrate
AT zhangpeng polytetraaquabis1himidazolekn3bis2oxaloaminobenzoato3dicopperiibariumiidihydrate

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