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N-Hydroxy-N-o-tolylacetamide
In the molecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intramolecular O—H⋯O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37 (3)° with respect...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960255/ https://www.ncbi.nlm.nih.gov/pubmed/21201552 http://dx.doi.org/10.1107/S1600536808002468 |
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author | Li, Yu-Hao Liu, Rui Zhang, Xiang-Ning Zhu, Hong-Jun |
author_facet | Li, Yu-Hao Liu, Rui Zhang, Xiang-Ning Zhu, Hong-Jun |
author_sort | Li, Yu-Hao |
collection | PubMed |
description | In the molecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intramolecular O—H⋯O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37 (3)° with respect to the benzene ring. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules stacked along the b axis. There are also π–π interactions between benzene rings with a face-to-face stacking distance of 3.434 Å. |
format | Text |
id | pubmed-2960255 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29602552010-12-30 N-Hydroxy-N-o-tolylacetamide Li, Yu-Hao Liu, Rui Zhang, Xiang-Ning Zhu, Hong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the molecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intramolecular O—H⋯O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37 (3)° with respect to the benzene ring. In the crystal structure, intermolecular O—H⋯O hydrogen bonds link the molecules stacked along the b axis. There are also π–π interactions between benzene rings with a face-to-face stacking distance of 3.434 Å. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960255/ /pubmed/21201552 http://dx.doi.org/10.1107/S1600536808002468 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Li, Yu-Hao Liu, Rui Zhang, Xiang-Ning Zhu, Hong-Jun N-Hydroxy-N-o-tolylacetamide |
title |
N-Hydroxy-N-o-tolylacetamide |
title_full |
N-Hydroxy-N-o-tolylacetamide |
title_fullStr |
N-Hydroxy-N-o-tolylacetamide |
title_full_unstemmed |
N-Hydroxy-N-o-tolylacetamide |
title_short |
N-Hydroxy-N-o-tolylacetamide |
title_sort | n-hydroxy-n-o-tolylacetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960255/ https://www.ncbi.nlm.nih.gov/pubmed/21201552 http://dx.doi.org/10.1107/S1600536808002468 |
work_keys_str_mv | AT liyuhao nhydroxynotolylacetamide AT liurui nhydroxynotolylacetamide AT zhangxiangning nhydroxynotolylacetamide AT zhuhongjun nhydroxynotolylacetamide |