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N-Hydr­oxy-N-o-tolyl­acetamide

In the mol­ecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intra­molecular O—H⋯O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37 (3)° with respect...

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Detalles Bibliográficos
Autores principales: Li, Yu-Hao, Liu, Rui, Zhang, Xiang-Ning, Zhu, Hong-Jun
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960255/
https://www.ncbi.nlm.nih.gov/pubmed/21201552
http://dx.doi.org/10.1107/S1600536808002468
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author Li, Yu-Hao
Liu, Rui
Zhang, Xiang-Ning
Zhu, Hong-Jun
author_facet Li, Yu-Hao
Liu, Rui
Zhang, Xiang-Ning
Zhu, Hong-Jun
author_sort Li, Yu-Hao
collection PubMed
description In the mol­ecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intra­molecular O—H⋯O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37 (3)° with respect to the benzene ring. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules stacked along the b axis. There are also π–π inter­actions between benzene rings with a face-to-face stacking distance of 3.434 Å.
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spelling pubmed-29602552010-12-30 N-Hydr­oxy-N-o-tolyl­acetamide Li, Yu-Hao Liu, Rui Zhang, Xiang-Ning Zhu, Hong-Jun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(9)H(11)NO(2), the methyl C atom bonded to the ring and the N atom lie in the benzene ring plane. An intra­molecular O—H⋯O hydrogen bond results in the formation of a five-membered planar ring, which is oriented at a dihedral angle of 81.37 (3)° with respect to the benzene ring. In the crystal structure, inter­molecular O—H⋯O hydrogen bonds link the mol­ecules stacked along the b axis. There are also π–π inter­actions between benzene rings with a face-to-face stacking distance of 3.434 Å. International Union of Crystallography 2008-01-30 /pmc/articles/PMC2960255/ /pubmed/21201552 http://dx.doi.org/10.1107/S1600536808002468 Text en © Li et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Li, Yu-Hao
Liu, Rui
Zhang, Xiang-Ning
Zhu, Hong-Jun
N-Hydr­oxy-N-o-tolyl­acetamide
title N-Hydr­oxy-N-o-tolyl­acetamide
title_full N-Hydr­oxy-N-o-tolyl­acetamide
title_fullStr N-Hydr­oxy-N-o-tolyl­acetamide
title_full_unstemmed N-Hydr­oxy-N-o-tolyl­acetamide
title_short N-Hydr­oxy-N-o-tolyl­acetamide
title_sort n-hydr­oxy-n-o-tolyl­acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960255/
https://www.ncbi.nlm.nih.gov/pubmed/21201552
http://dx.doi.org/10.1107/S1600536808002468
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AT zhuhongjun nhydroxynotolylacetamide