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Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)

In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa­hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl­glyoxime and dimethyl­glyoximate ligands, while the two axial positions are occupied b...

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Detalles Bibliográficos
Autores principales: Ramesh, P., SubbiahPandi, A., Jothi, P., Revathi, C., Dayalan, A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960257/
https://www.ncbi.nlm.nih.gov/pubmed/21201276
http://dx.doi.org/10.1107/S1600536807068407
Descripción
Sumario:In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa­hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl­glyoxime and dimethyl­glyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intra­molecular O—H⋯O hydrogen bonds are observed between the dimethyl­glyoxime and dimethyl­glyoximate ligands. Mol­ecules are linked into a chain running along the [101] direction by O—H⋯O and C—H⋯Cl hydrogen bonds. The chains are cross-linked through inter­molecular C—H⋯Cl hydrogen bonds.