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Dichlorido(dimethylglyoximato-κ(2) N,N′)(dimethylglyoxime-κ(2) N,N′)cobalt(III)
In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octahedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethylglyoxime and dimethylglyoximate ligands, while the two axial positions are occupied b...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960257/ https://www.ncbi.nlm.nih.gov/pubmed/21201276 http://dx.doi.org/10.1107/S1600536807068407 |
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author | Ramesh, P. SubbiahPandi, A. Jothi, P. Revathi, C. Dayalan, A. |
author_facet | Ramesh, P. SubbiahPandi, A. Jothi, P. Revathi, C. Dayalan, A. |
author_sort | Ramesh, P. |
collection | PubMed |
description | In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octahedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethylglyoxime and dimethylglyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intramolecular O—H⋯O hydrogen bonds are observed between the dimethylglyoxime and dimethylglyoximate ligands. Molecules are linked into a chain running along the [101] direction by O—H⋯O and C—H⋯Cl hydrogen bonds. The chains are cross-linked through intermolecular C—H⋯Cl hydrogen bonds. |
format | Text |
id | pubmed-2960257 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29602572010-12-30 Dichlorido(dimethylglyoximato-κ(2) N,N′)(dimethylglyoxime-κ(2) N,N′)cobalt(III) Ramesh, P. SubbiahPandi, A. Jothi, P. Revathi, C. Dayalan, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octahedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethylglyoxime and dimethylglyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intramolecular O—H⋯O hydrogen bonds are observed between the dimethylglyoxime and dimethylglyoximate ligands. Molecules are linked into a chain running along the [101] direction by O—H⋯O and C—H⋯Cl hydrogen bonds. The chains are cross-linked through intermolecular C—H⋯Cl hydrogen bonds. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960257/ /pubmed/21201276 http://dx.doi.org/10.1107/S1600536807068407 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Ramesh, P. SubbiahPandi, A. Jothi, P. Revathi, C. Dayalan, A. Dichlorido(dimethylglyoximato-κ(2) N,N′)(dimethylglyoxime-κ(2) N,N′)cobalt(III) |
title | Dichlorido(dimethylglyoximato-κ(2)
N,N′)(dimethylglyoxime-κ(2)
N,N′)cobalt(III) |
title_full | Dichlorido(dimethylglyoximato-κ(2)
N,N′)(dimethylglyoxime-κ(2)
N,N′)cobalt(III) |
title_fullStr | Dichlorido(dimethylglyoximato-κ(2)
N,N′)(dimethylglyoxime-κ(2)
N,N′)cobalt(III) |
title_full_unstemmed | Dichlorido(dimethylglyoximato-κ(2)
N,N′)(dimethylglyoxime-κ(2)
N,N′)cobalt(III) |
title_short | Dichlorido(dimethylglyoximato-κ(2)
N,N′)(dimethylglyoxime-κ(2)
N,N′)cobalt(III) |
title_sort | dichlorido(dimethylglyoximato-κ(2)
n,n′)(dimethylglyoxime-κ(2)
n,n′)cobalt(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960257/ https://www.ncbi.nlm.nih.gov/pubmed/21201276 http://dx.doi.org/10.1107/S1600536807068407 |
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