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Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)

In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa­hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl­glyoxime and dimethyl­glyoximate ligands, while the two axial positions are occupied b...

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Detalles Bibliográficos
Autores principales: Ramesh, P., SubbiahPandi, A., Jothi, P., Revathi, C., Dayalan, A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960257/
https://www.ncbi.nlm.nih.gov/pubmed/21201276
http://dx.doi.org/10.1107/S1600536807068407
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author Ramesh, P.
SubbiahPandi, A.
Jothi, P.
Revathi, C.
Dayalan, A.
author_facet Ramesh, P.
SubbiahPandi, A.
Jothi, P.
Revathi, C.
Dayalan, A.
author_sort Ramesh, P.
collection PubMed
description In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa­hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl­glyoxime and dimethyl­glyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intra­molecular O—H⋯O hydrogen bonds are observed between the dimethyl­glyoxime and dimethyl­glyoximate ligands. Mol­ecules are linked into a chain running along the [101] direction by O—H⋯O and C—H⋯Cl hydrogen bonds. The chains are cross-linked through inter­molecular C—H⋯Cl hydrogen bonds.
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spelling pubmed-29602572010-12-30 Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III) Ramesh, P. SubbiahPandi, A. Jothi, P. Revathi, C. Dayalan, A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(C(4)H(7)N(2)O(2))Cl(2)(C(4)H(8)N(2)O(2))], the Co(III) ion has a distorted octa­hedral coordination environment. The equatorial plane consists of four N atoms, two each from the dimethyl­glyoxime and dimethyl­glyoximate ligands, while the two axial positions are occupied by two chloride ions. Strong intra­molecular O—H⋯O hydrogen bonds are observed between the dimethyl­glyoxime and dimethyl­glyoximate ligands. Mol­ecules are linked into a chain running along the [101] direction by O—H⋯O and C—H⋯Cl hydrogen bonds. The chains are cross-linked through inter­molecular C—H⋯Cl hydrogen bonds. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960257/ /pubmed/21201276 http://dx.doi.org/10.1107/S1600536807068407 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Ramesh, P.
SubbiahPandi, A.
Jothi, P.
Revathi, C.
Dayalan, A.
Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)
title Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)
title_full Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)
title_fullStr Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)
title_full_unstemmed Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)
title_short Dichlorido(dimethyl­glyoximato-κ(2) N,N′)(dimethyl­glyoxime-κ(2) N,N′)cobalt(III)
title_sort dichlorido(dimethyl­glyoximato-κ(2) n,n′)(dimethyl­glyoxime-κ(2) n,n′)cobalt(iii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960257/
https://www.ncbi.nlm.nih.gov/pubmed/21201276
http://dx.doi.org/10.1107/S1600536807068407
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