Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title complex, [Cu(C(2)H(2)ClO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2) Å] from two 2-chloro­acetate ligands and one water mol­ecule [Cu—O =...

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Detalles Bibliográficos
Autores principales: Yang, Rongdong, Li, Yanfei, Sun, Junshan, Li, Jikun, Chu, Changqing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960263/
https://www.ncbi.nlm.nih.gov/pubmed/21201309
http://dx.doi.org/10.1107/S1600536808000044
Descripción
Sumario:In the title complex, [Cu(C(2)H(2)ClO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2) Å] from two 2-chloro­acetate ligands and one water mol­ecule [Cu—O = 2.253 (2) Å] in a distorted square-pyramidal geometry. The crystal structure exhibits inter­molecular O—H⋯O hydrogen bonds, short Cl⋯Cl contacts [3.334 (1) Å] and π–π inter­actions [centroid–centroid distance 3.621 (11) Å].

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