Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)

In the title complex, [Cu(C(2)H(2)ClO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2) Å] from two 2-chloro­acetate ligands and one water mol­ecule [Cu—O =...

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Detalles Bibliográficos
Autores principales: Yang, Rongdong, Li, Yanfei, Sun, Junshan, Li, Jikun, Chu, Changqing
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960263/
https://www.ncbi.nlm.nih.gov/pubmed/21201309
http://dx.doi.org/10.1107/S1600536808000044
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author Yang, Rongdong
Li, Yanfei
Sun, Junshan
Li, Jikun
Chu, Changqing
author_facet Yang, Rongdong
Li, Yanfei
Sun, Junshan
Li, Jikun
Chu, Changqing
author_sort Yang, Rongdong
collection PubMed
description In the title complex, [Cu(C(2)H(2)ClO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2) Å] from two 2-chloro­acetate ligands and one water mol­ecule [Cu—O = 2.253 (2) Å] in a distorted square-pyramidal geometry. The crystal structure exhibits inter­molecular O—H⋯O hydrogen bonds, short Cl⋯Cl contacts [3.334 (1) Å] and π–π inter­actions [centroid–centroid distance 3.621 (11) Å].
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spelling pubmed-29602632010-12-30 Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II) Yang, Rongdong Li, Yanfei Sun, Junshan Li, Jikun Chu, Changqing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(2)H(2)ClO(2))(2)(C(12)H(8)N(2))(H(2)O)], the Cu(II) ion is five-coordinated by two N atoms [Cu—N = 2.005 (2) and 2.029 (2) Å] from the 1,10-phenanthroline ligand, two O atoms [Cu—O = 1.943 (2)–1.966 (2) Å] from two 2-chloro­acetate ligands and one water mol­ecule [Cu—O = 2.253 (2) Å] in a distorted square-pyramidal geometry. The crystal structure exhibits inter­molecular O—H⋯O hydrogen bonds, short Cl⋯Cl contacts [3.334 (1) Å] and π–π inter­actions [centroid–centroid distance 3.621 (11) Å]. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960263/ /pubmed/21201309 http://dx.doi.org/10.1107/S1600536808000044 Text en © Yang et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yang, Rongdong
Li, Yanfei
Sun, Junshan
Li, Jikun
Chu, Changqing
Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_fullStr Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_full_unstemmed Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_short Aqua­bis(2-chloro­acetato-κO)(1,10-phenanthroline-κ(2) N,N′)copper(II)
title_sort aqua­bis(2-chloro­acetato-κo)(1,10-phenanthroline-κ(2) n,n′)copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960263/
https://www.ncbi.nlm.nih.gov/pubmed/21201309
http://dx.doi.org/10.1107/S1600536808000044
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AT sunjunshan aquabis2chloroacetatoko110phenanthrolinek2nncopperii
AT lijikun aquabis2chloroacetatoko110phenanthrolinek2nncopperii
AT chuchangqing aquabis2chloroacetatoko110phenanthrolinek2nncopperii

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