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Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II)

In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octa­hedral geometry by two O atoms from two 2-oxo-1,2-dihydro­quinoline-4-carboxyl­ate ligands and four water mol­ecules, all of which act as m...

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Detalles Bibliográficos
Autores principales: Yuan, Gang, Qin, Jun-Sheng, Su, Zhong-Min, Shao, Kui-Zhan, Fu, Yao-Mei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960272/
https://www.ncbi.nlm.nih.gov/pubmed/21201341
http://dx.doi.org/10.1107/S1600536807065671
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author Yuan, Gang
Qin, Jun-Sheng
Su, Zhong-Min
Shao, Kui-Zhan
Fu, Yao-Mei
author_facet Yuan, Gang
Qin, Jun-Sheng
Su, Zhong-Min
Shao, Kui-Zhan
Fu, Yao-Mei
author_sort Yuan, Gang
collection PubMed
description In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octa­hedral geometry by two O atoms from two 2-oxo-1,2-dihydro­quinoline-4-carboxyl­ate ligands and four water mol­ecules, all of which act as monodentate ligands. The crystal structure features an extensive network of inter­molecular hydrogen-bonding inter­actions (O—H⋯O and N—H⋯O) and offset face-to-face π–π stacking inter­actions [centroid–centroid distances = 3.525 (3) and 3.281 (5) Å].
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spelling pubmed-29602722010-12-30 Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II) Yuan, Gang Qin, Jun-Sheng Su, Zhong-Min Shao, Kui-Zhan Fu, Yao-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octa­hedral geometry by two O atoms from two 2-oxo-1,2-dihydro­quinoline-4-carboxyl­ate ligands and four water mol­ecules, all of which act as monodentate ligands. The crystal structure features an extensive network of inter­molecular hydrogen-bonding inter­actions (O—H⋯O and N—H⋯O) and offset face-to-face π–π stacking inter­actions [centroid–centroid distances = 3.525 (3) and 3.281 (5) Å]. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960272/ /pubmed/21201341 http://dx.doi.org/10.1107/S1600536807065671 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Yuan, Gang
Qin, Jun-Sheng
Su, Zhong-Min
Shao, Kui-Zhan
Fu, Yao-Mei
Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II)
title Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II)
title_full Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II)
title_fullStr Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II)
title_full_unstemmed Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II)
title_short Tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κO (4))nickel(II)
title_sort tetra­aqua­bis(2-oxo-1,2-dihydro­quinoline-4-carboxyl­ato-κo (4))nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960272/
https://www.ncbi.nlm.nih.gov/pubmed/21201341
http://dx.doi.org/10.1107/S1600536807065671
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