Cargando…
Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO (4))nickel(II)
In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octahedral geometry by two O atoms from two 2-oxo-1,2-dihydroquinoline-4-carboxylate ligands and four water molecules, all of which act as m...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960272/ https://www.ncbi.nlm.nih.gov/pubmed/21201341 http://dx.doi.org/10.1107/S1600536807065671 |
_version_ | 1782188699592687616 |
---|---|
author | Yuan, Gang Qin, Jun-Sheng Su, Zhong-Min Shao, Kui-Zhan Fu, Yao-Mei |
author_facet | Yuan, Gang Qin, Jun-Sheng Su, Zhong-Min Shao, Kui-Zhan Fu, Yao-Mei |
author_sort | Yuan, Gang |
collection | PubMed |
description | In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octahedral geometry by two O atoms from two 2-oxo-1,2-dihydroquinoline-4-carboxylate ligands and four water molecules, all of which act as monodentate ligands. The crystal structure features an extensive network of intermolecular hydrogen-bonding interactions (O—H⋯O and N—H⋯O) and offset face-to-face π–π stacking interactions [centroid–centroid distances = 3.525 (3) and 3.281 (5) Å]. |
format | Text |
id | pubmed-2960272 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29602722010-12-30 Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO (4))nickel(II) Yuan, Gang Qin, Jun-Sheng Su, Zhong-Min Shao, Kui-Zhan Fu, Yao-Mei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Ni(C(10)H(6)NO(3))(2)(H(2)O)(4)], the central Ni(II) atom is located on an inversion center and coordinated in a slightly distorted octahedral geometry by two O atoms from two 2-oxo-1,2-dihydroquinoline-4-carboxylate ligands and four water molecules, all of which act as monodentate ligands. The crystal structure features an extensive network of intermolecular hydrogen-bonding interactions (O—H⋯O and N—H⋯O) and offset face-to-face π–π stacking interactions [centroid–centroid distances = 3.525 (3) and 3.281 (5) Å]. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960272/ /pubmed/21201341 http://dx.doi.org/10.1107/S1600536807065671 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Yuan, Gang Qin, Jun-Sheng Su, Zhong-Min Shao, Kui-Zhan Fu, Yao-Mei Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO (4))nickel(II) |
title | Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO
(4))nickel(II) |
title_full | Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO
(4))nickel(II) |
title_fullStr | Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO
(4))nickel(II) |
title_full_unstemmed | Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO
(4))nickel(II) |
title_short | Tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κO
(4))nickel(II) |
title_sort | tetraaquabis(2-oxo-1,2-dihydroquinoline-4-carboxylato-κo
(4))nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960272/ https://www.ncbi.nlm.nih.gov/pubmed/21201341 http://dx.doi.org/10.1107/S1600536807065671 |
work_keys_str_mv | AT yuangang tetraaquabis2oxo12dihydroquinoline4carboxylatoko4nickelii AT qinjunsheng tetraaquabis2oxo12dihydroquinoline4carboxylatoko4nickelii AT suzhongmin tetraaquabis2oxo12dihydroquinoline4carboxylatoko4nickelii AT shaokuizhan tetraaquabis2oxo12dihydroquinoline4carboxylatoko4nickelii AT fuyaomei tetraaquabis2oxo12dihydroquinoline4carboxylatoko4nickelii |