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{2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II)

The central Ni atom of the title compound, [Ni(C(29)H(29)N(3)O(4))], is coordinated by three N atoms [Ni—N = 1.955 (2), 1.844 (2) and 1.872 (2) Å] and by one O atom [Ni—O = 1.862 (2) Å] in a pseudo-square-planar geometry. The conformation of the hydroxy­butanoate side chain is controlled by a strong...

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Detalles Bibliográficos
Autores principales: Popkov, Alexander, Nádvorník, Milan, Kožíšek, Jozef
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960276/
https://www.ncbi.nlm.nih.gov/pubmed/21201323
http://dx.doi.org/10.1107/S1600536808000949
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author Popkov, Alexander
Nádvorník, Milan
Kožíšek, Jozef
author_facet Popkov, Alexander
Nádvorník, Milan
Kožíšek, Jozef
author_sort Popkov, Alexander
collection PubMed
description The central Ni atom of the title compound, [Ni(C(29)H(29)N(3)O(4))], is coordinated by three N atoms [Ni—N = 1.955 (2), 1.844 (2) and 1.872 (2) Å] and by one O atom [Ni—O = 1.862 (2) Å] in a pseudo-square-planar geometry. The conformation of the hydroxy­butanoate side chain is controlled by a strong intra­molecular hydrogen bond (H⋯O = 1.84 Å).
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spelling pubmed-29602762010-12-30 {2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II) Popkov, Alexander Nádvorník, Milan Kožíšek, Jozef Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The central Ni atom of the title compound, [Ni(C(29)H(29)N(3)O(4))], is coordinated by three N atoms [Ni—N = 1.955 (2), 1.844 (2) and 1.872 (2) Å] and by one O atom [Ni—O = 1.862 (2) Å] in a pseudo-square-planar geometry. The conformation of the hydroxy­butanoate side chain is controlled by a strong intra­molecular hydrogen bond (H⋯O = 1.84 Å). International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960276/ /pubmed/21201323 http://dx.doi.org/10.1107/S1600536808000949 Text en © Popkov et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Popkov, Alexander
Nádvorník, Milan
Kožíšek, Jozef
{2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II)
title {2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II)
title_full {2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II)
title_fullStr {2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II)
title_full_unstemmed {2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II)
title_short {2-[(S)-({2-[(S)-1-Benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) N,N′,N′′,O}nickel(II)
title_sort {2-[(s)-({2-[(s)-1-benzyl­pyrrolidine-2-carboxamido]phen­yl}(phen­yl)methyl­ene)amino]-4-hydroxy­butanoato-κ(4) n,n′,n′′,o}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960276/
https://www.ncbi.nlm.nih.gov/pubmed/21201323
http://dx.doi.org/10.1107/S1600536808000949
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