Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)

The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa­molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2′-bipyridine and a 2-amino­...

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Detalles Bibliográficos
Autores principales: Liu, Haiyan, Zhang, Yunjie, Yu, Decheng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960279/
https://www.ncbi.nlm.nih.gov/pubmed/21201279
http://dx.doi.org/10.1107/S1600536808000020
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author Liu, Haiyan
Zhang, Yunjie
Yu, Decheng
author_facet Liu, Haiyan
Zhang, Yunjie
Yu, Decheng
author_sort Liu, Haiyan
collection PubMed
description The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa­molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2′-bipyridine and a 2-amino­acetate ligands in the basal plane and by an O atom of N,N-dimethyl­formamide in the apical position. The anions and cations are linked by N—H⋯O hydrogen bonds into a three-dimensional network.
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spelling pubmed-29602792010-12-30 Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI) Liu, Haiyan Zhang, Yunjie Yu, Decheng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (NH(4))(2)[Cu(C(2)H(4)NO(2))(C(10)H(8)N(2))(C(3)H(7)NO)](2)[Mo(8)O(26)], contains a centrosymmetric β-type octa­molybdate anion, two copper(II) complex cations and two ammonium ions. The Cu(II) atom is coordinated in a square-pyramidal geometry by a 2,2′-bipyridine and a 2-amino­acetate ligands in the basal plane and by an O atom of N,N-dimethyl­formamide in the apical position. The anions and cations are linked by N—H⋯O hydrogen bonds into a three-dimensional network. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960279/ /pubmed/21201279 http://dx.doi.org/10.1107/S1600536808000020 Text en © Liu et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Liu, Haiyan
Zhang, Yunjie
Yu, Decheng
Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)
title Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)
title_full Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)
title_fullStr Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)
title_full_unstemmed Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)
title_short Diammonium bis­[(2-amino­acetato-κ(2) N,O)(2,2′-bipyridine-κ(2) N,N′)(N,N-dimethyl­formamide-κO)copper(II)] hexa­cosa­oxidoocta­molybdate(VI)
title_sort diammonium bis­[(2-amino­acetato-κ(2) n,o)(2,2′-bipyridine-κ(2) n,n′)(n,n-dimethyl­formamide-κo)copper(ii)] hexa­cosa­oxidoocta­molybdate(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960279/
https://www.ncbi.nlm.nih.gov/pubmed/21201279
http://dx.doi.org/10.1107/S1600536808000020
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AT zhangyunjie diammoniumbis2aminoacetatok2no22bipyridinek2nnnndimethylformamidekocopperiihexacosaoxidooctamolybdatevi
AT yudecheng diammoniumbis2aminoacetatok2no22bipyridinek2nnnndimethylformamidekocopperiihexacosaoxidooctamolybdatevi

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