(Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate

The title compound, C(12)H(12)Cl(2)N(2)O(3), crystallizes as a non-merohedral twin with a twinning ratio of 0.51:0.49. The mol­ecule adopts a keto–hydrazo tautomeric form stabilized by an intra­molecular N—H⋯O hydrogen bond. The configuration around the N—N bond is trans.

Detalles Bibliográficos
Autores principales: Alpaslan, Gökhan, Özdamar, Özgür, Odabaşoğlu, Mustafa, Büyükgüngör, Orhan, Erdönmez, Ahmet
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960280/
https://www.ncbi.nlm.nih.gov/pubmed/21201455
http://dx.doi.org/10.1107/S1600536807065300
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author Alpaslan, Gökhan
Özdamar, Özgür
Odabaşoğlu, Mustafa
Büyükgüngör, Orhan
Erdönmez, Ahmet
author_facet Alpaslan, Gökhan
Özdamar, Özgür
Odabaşoğlu, Mustafa
Büyükgüngör, Orhan
Erdönmez, Ahmet
author_sort Alpaslan, Gökhan
collection PubMed
description The title compound, C(12)H(12)Cl(2)N(2)O(3), crystallizes as a non-merohedral twin with a twinning ratio of 0.51:0.49. The mol­ecule adopts a keto–hydrazo tautomeric form stabilized by an intra­molecular N—H⋯O hydrogen bond. The configuration around the N—N bond is trans.
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spelling pubmed-29602802010-12-30 (Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate Alpaslan, Gökhan Özdamar, Özgür Odabaşoğlu, Mustafa Büyükgüngör, Orhan Erdönmez, Ahmet Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(12)H(12)Cl(2)N(2)O(3), crystallizes as a non-merohedral twin with a twinning ratio of 0.51:0.49. The mol­ecule adopts a keto–hydrazo tautomeric form stabilized by an intra­molecular N—H⋯O hydrogen bond. The configuration around the N—N bond is trans. International Union of Crystallography 2008-01-11 /pmc/articles/PMC2960280/ /pubmed/21201455 http://dx.doi.org/10.1107/S1600536807065300 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Alpaslan, Gökhan
Özdamar, Özgür
Odabaşoğlu, Mustafa
Büyükgüngör, Orhan
Erdönmez, Ahmet
(Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate
title (Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate
title_full (Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate
title_fullStr (Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate
title_full_unstemmed (Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate
title_short (Z)-Ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate
title_sort (z)-ethyl 4-chloro-2-[(4-chloro­phen­yl)hydrazono]-3-oxobutanoate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960280/
https://www.ncbi.nlm.nih.gov/pubmed/21201455
http://dx.doi.org/10.1107/S1600536807065300
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