Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II))

The title complex, [Ni(2)(C(11)H(11)Br(2)N(2)O)(2)(NCS)(2)], is a thio­cyanate-bridged dinuclear nickel(II) complex. The asymmetric unit contains two molecules. Both Ni atoms in each molecule have a square-pyramidal coordination geometry, and each center is bound by one O and two N atoms of one Schi...

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Detalles Bibliográficos
Autor principal: Lin, Hong-Wei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960283/
https://www.ncbi.nlm.nih.gov/pubmed/21201272
http://dx.doi.org/10.1107/S1600536807068146
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author Lin, Hong-Wei
author_facet Lin, Hong-Wei
author_sort Lin, Hong-Wei
collection PubMed
description The title complex, [Ni(2)(C(11)H(11)Br(2)N(2)O)(2)(NCS)(2)], is a thio­cyanate-bridged dinuclear nickel(II) complex. The asymmetric unit contains two molecules. Both Ni atoms in each molecule have a square-pyramidal coordination geometry, and each center is bound by one O and two N atoms of one Schiff base ligand and by one N atom of a bridging thio­cyanate ligand, which define the basal planes. N atoms from the bridging thio­cyanate ligands occupy the apical positions.
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spelling pubmed-29602832010-12-30 Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II)) Lin, Hong-Wei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Ni(2)(C(11)H(11)Br(2)N(2)O)(2)(NCS)(2)], is a thio­cyanate-bridged dinuclear nickel(II) complex. The asymmetric unit contains two molecules. Both Ni atoms in each molecule have a square-pyramidal coordination geometry, and each center is bound by one O and two N atoms of one Schiff base ligand and by one N atom of a bridging thio­cyanate ligand, which define the basal planes. N atoms from the bridging thio­cyanate ligands occupy the apical positions. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960283/ /pubmed/21201272 http://dx.doi.org/10.1107/S1600536807068146 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Lin, Hong-Wei
Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II))
title Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II))
title_full Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II))
title_fullStr Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II))
title_full_unstemmed Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II))
title_short Di-μ-thio­cyanato-κ(4) N:N-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) N,N′,O}nickel(II))
title_sort di-μ-thio­cyanato-κ(4) n:n-bis­({2,4-di­bromo-6-[2-(methyl­amino)ethyl­imino­meth­yl]­phenol­ato-κ(3) n,n′,o}nickel(ii))
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960283/
https://www.ncbi.nlm.nih.gov/pubmed/21201272
http://dx.doi.org/10.1107/S1600536807068146
work_keys_str_mv AT linhongwei dimthiocyanatok4nnbis24dibromo62methylaminoethyliminomethylphenolatok3nnonickelii

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