Poly[[hexa-μ-cyanido-manganese(II)iron(III)] penta­hydrate]

The structure of the title compound, Mn(II)[Fe(III)(CN)(6)](2/3)·5H(2)O, features a face-centered cubic –Mn—NC—Fe– framework with both Mn and Fe having site symmetry m [Image: see text] m. Since one-third of the [Fe(CN)(6)](3−) units are missing for a given formula in order to maintain charge neutrality, each Mn atom around such a vacancy is coordinated not only by the N atoms of the CN groups but also by the O atoms of the ligand water mol­ecules. In addition to ligand water mol­ecules, two types of non-coordinated water mol­ecules, so-called zeolitic water mol­ecules, exist in the inter­stitial sites of the –Mn—NC—Fe– framework. The positions of the O atoms of the zeolitic water mol­ecules are fixed by the linkage via hydrogen bonds between ligand water and zeolitic water mol­ecules. The structure is related to a recently reported rubidium manganese hexa­cyano­ferrate. Site occupancy factors for Fe, C, N are 0.67; for two O atoms the value is 0.83 and for one O atom is 0.17.