Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)

The title compound, (CH(6)N)(2)[WS(4)], was synthesized by the reaction of ammonium tetra­sulfidotungstate(VI) with aqueous methyl­amine. The title compound is isotypic with the corresponding Mo analogue (CH(6)N)(2)[MoS(4)], and its structure consists of a slightly distorted tetra­hedral [WS(4)](2−)...

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Detalles Bibliográficos
Autores principales: Srinivasan, Bikshandarkoil R., Näther, Christian, Bensch, Wolfgang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960287/
https://www.ncbi.nlm.nih.gov/pubmed/21201273
http://dx.doi.org/10.1107/S1600536807067682
Descripción
Sumario:The title compound, (CH(6)N)(2)[WS(4)], was synthesized by the reaction of ammonium tetra­sulfidotungstate(VI) with aqueous methyl­amine. The title compound is isotypic with the corresponding Mo analogue (CH(6)N)(2)[MoS(4)], and its structure consists of a slightly distorted tetra­hedral [WS(4)](2−) dianion and two crystallographically independent methyl­ammonium (MeNH(3)) cations, all of which are located on crystallographic mirror planes. The tetra­sulfidotungstate anions are linked to the organic cations via hydrogen-bonding inter­actions.

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