Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)

The title compound, (CH(6)N)(2)[WS(4)], was synthesized by the reaction of ammonium tetra­sulfidotungstate(VI) with aqueous methyl­amine. The title compound is isotypic with the corresponding Mo analogue (CH(6)N)(2)[MoS(4)], and its structure consists of a slightly distorted tetra­hedral [WS(4)](2−)...

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Detalles Bibliográficos
Autores principales: Srinivasan, Bikshandarkoil R., Näther, Christian, Bensch, Wolfgang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960287/
https://www.ncbi.nlm.nih.gov/pubmed/21201273
http://dx.doi.org/10.1107/S1600536807067682
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author Srinivasan, Bikshandarkoil R.
Näther, Christian
Bensch, Wolfgang
author_facet Srinivasan, Bikshandarkoil R.
Näther, Christian
Bensch, Wolfgang
author_sort Srinivasan, Bikshandarkoil R.
collection PubMed
description The title compound, (CH(6)N)(2)[WS(4)], was synthesized by the reaction of ammonium tetra­sulfidotungstate(VI) with aqueous methyl­amine. The title compound is isotypic with the corresponding Mo analogue (CH(6)N)(2)[MoS(4)], and its structure consists of a slightly distorted tetra­hedral [WS(4)](2−) dianion and two crystallographically independent methyl­ammonium (MeNH(3)) cations, all of which are located on crystallographic mirror planes. The tetra­sulfidotungstate anions are linked to the organic cations via hydrogen-bonding inter­actions.
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spelling pubmed-29602872010-12-30 Bis(methyl­ammonium) tetra­sulfido­tungstate(VI) Srinivasan, Bikshandarkoil R. Näther, Christian Bensch, Wolfgang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (CH(6)N)(2)[WS(4)], was synthesized by the reaction of ammonium tetra­sulfidotungstate(VI) with aqueous methyl­amine. The title compound is isotypic with the corresponding Mo analogue (CH(6)N)(2)[MoS(4)], and its structure consists of a slightly distorted tetra­hedral [WS(4)](2−) dianion and two crystallographically independent methyl­ammonium (MeNH(3)) cations, all of which are located on crystallographic mirror planes. The tetra­sulfidotungstate anions are linked to the organic cations via hydrogen-bonding inter­actions. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960287/ /pubmed/21201273 http://dx.doi.org/10.1107/S1600536807067682 Text en © Srinivasan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Srinivasan, Bikshandarkoil R.
Näther, Christian
Bensch, Wolfgang
Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)
title Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)
title_full Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)
title_fullStr Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)
title_full_unstemmed Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)
title_short Bis(methyl­ammonium) tetra­sulfido­tungstate(VI)
title_sort bis(methyl­ammonium) tetra­sulfido­tungstate(vi)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960287/
https://www.ncbi.nlm.nih.gov/pubmed/21201273
http://dx.doi.org/10.1107/S1600536807067682
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AT natherchristian bismethylammoniumtetrasulfidotungstatevi
AT benschwolfgang bismethylammoniumtetrasulfidotungstatevi

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