[2,6-Bis(5-chloro­pyrimidin-2-yl-κN)pyri­dine-κN](2,2′:6′,2′′-terpyridine-κ(3) N,N′,N′′)ruthenium(II) bis­(hexa­fluoridophosphate) acetonitrile disolvate

In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octa­hedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis­(5-chloro­pyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortion...

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Detalles Bibliográficos
Autores principales: Medlycott, Elaine A., Wang, Jianhua, Hanan, Garry S.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960288/
https://www.ncbi.nlm.nih.gov/pubmed/21201294
http://dx.doi.org/10.1107/S1600536807068602
Descripción
Sumario:In the title compound, [Ru(C(13)H(7)Cl(2)N(5))(C(15)H(11)N(3))](PF(6))(2)·2CH(3)CN, the Ru(II) atom is coordinated in a distorted octa­hedral geometry by a tridentate 2,2′:6′,2′′-terpyridine ligand and a tridentate 2,6-bis­(5-chloro­pyrimidin-2-yl)pyridine ligand. Least-squares mean-plane distortions of only 1.72 (2) and 2.91 (2)° of the pyrimidyl rings with respect to the central pyridine are observed for the bis­(pyrimid­yl)pyridine-based tridentate ligand, while the distal pyridyl rings of terpyridine twist by 13.43 (7) and 4.68 (9)° away from the central pyridine ring.

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