4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene

In the title compound, C(29)H(25)NS(2), both the Cl atoms of the aza­diene precursor 4,4-dichloro-1,1-diphenyl-2-aza­buta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a π-conjugated 2-aza­butadiene array. The aza­diene chain is planar to within 0.01...

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Detalles Bibliográficos
Autores principales: Kinghat, Rodolphe, Boudiba, Hamid, Khatyr, Abderrahim, Knorr, Michael, Kubicki, Marek M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960289/
https://www.ncbi.nlm.nih.gov/pubmed/21201402
http://dx.doi.org/10.1107/S1600536807066615
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author Kinghat, Rodolphe
Boudiba, Hamid
Khatyr, Abderrahim
Knorr, Michael
Kubicki, Marek M.
author_facet Kinghat, Rodolphe
Boudiba, Hamid
Khatyr, Abderrahim
Knorr, Michael
Kubicki, Marek M.
author_sort Kinghat, Rodolphe
collection PubMed
description In the title compound, C(29)H(25)NS(2), both the Cl atoms of the aza­diene precursor 4,4-dichloro-1,1-diphenyl-2-aza­buta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a π-conjugated 2-aza­butadiene array. The aza­diene chain is planar to within 0.01 Å. One of the phenyl rings seems to be slightly π-conjugated with the aza­diene core [dihedral angle 5.1 (2)°].
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spelling pubmed-29602892010-12-30 4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene Kinghat, Rodolphe Boudiba, Hamid Khatyr, Abderrahim Knorr, Michael Kubicki, Marek M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(29)H(25)NS(2), both the Cl atoms of the aza­diene precursor 4,4-dichloro-1,1-diphenyl-2-aza­buta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a π-conjugated 2-aza­butadiene array. The aza­diene chain is planar to within 0.01 Å. One of the phenyl rings seems to be slightly π-conjugated with the aza­diene core [dihedral angle 5.1 (2)°]. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960289/ /pubmed/21201402 http://dx.doi.org/10.1107/S1600536807066615 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Kinghat, Rodolphe
Boudiba, Hamid
Khatyr, Abderrahim
Knorr, Michael
Kubicki, Marek M.
4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene
title 4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene
title_full 4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene
title_fullStr 4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene
title_full_unstemmed 4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene
title_short 4,4-Bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene
title_sort 4,4-bis(4-methyl­phenyl­sulfan­yl)-1,1-diphenyl-2-aza­buta-1,3-diene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960289/
https://www.ncbi.nlm.nih.gov/pubmed/21201402
http://dx.doi.org/10.1107/S1600536807066615
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