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Bis[μ-1,2-bis­(diphenyl­phosphino)methane-κ(2) P:P′]bis­[(η(2)-ethene)nickel(0)] toluene disolvate

In the title compound, [Ni(2)(C(2)H(4))(2)(C(25)H(22)P(2))(2)]·2C(7)H(8), each Ni atom is coordinated in a trigonal-planar geometry by two P atoms of the bridging 1,2-bis­(diphenyl­phosphino)methane (dppm) ligands and by the centroid of the double bond of an ethene ligand. An eight-membered ring com...

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Detalles Bibliográficos
Autores principales: Langer, Jens, Fischer, Reinhald, Görls, Helmar, Walther, Dirk
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960292/
https://www.ncbi.nlm.nih.gov/pubmed/21201358
http://dx.doi.org/10.1107/S1600536808002110
Descripción
Sumario:In the title compound, [Ni(2)(C(2)H(4))(2)(C(25)H(22)P(2))(2)]·2C(7)H(8), each Ni atom is coordinated in a trigonal-planar geometry by two P atoms of the bridging 1,2-bis­(diphenyl­phosphino)methane (dppm) ligands and by the centroid of the double bond of an ethene ligand. An eight-membered ring comprising the two Ni atoms, four P atoms and the CH(2) groups of the two dppm ligands is thus formed. The methyl group in one of the solvent toluene mol­ecules is disordered over two positions with equal occupancies.