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Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)

The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra­coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol­ecules dimerize through a nonbonded S⋯S inter­action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the cryst...

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Detalles Bibliográficos
Autores principales: Bagchi, Vivek, Bandyopadhyay, Debkumar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960293/
https://www.ncbi.nlm.nih.gov/pubmed/21201318
http://dx.doi.org/10.1107/S1600536808000767
Descripción
Sumario:The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra­coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol­ecules dimerize through a nonbonded S⋯S inter­action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter­molecular π–π inter­actions; the centroid–centroid distances are 3.804 (3), 3.638 (3), 3.804 (3) and 3.638 (3) Å, and the corresponding perpendicular distances are 3.369, 3.448, 3.406 and 3.466 Å.