Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)

The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra­coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol­ecules dimerize through a nonbonded S⋯S inter­action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the cryst...

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Detalles Bibliográficos
Autores principales: Bagchi, Vivek, Bandyopadhyay, Debkumar
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960293/
https://www.ncbi.nlm.nih.gov/pubmed/21201318
http://dx.doi.org/10.1107/S1600536808000767
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author Bagchi, Vivek
Bandyopadhyay, Debkumar
author_facet Bagchi, Vivek
Bandyopadhyay, Debkumar
author_sort Bagchi, Vivek
collection PubMed
description The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra­coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol­ecules dimerize through a nonbonded S⋯S inter­action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter­molecular π–π inter­actions; the centroid–centroid distances are 3.804 (3), 3.638 (3), 3.804 (3) and 3.638 (3) Å, and the corresponding perpendicular distances are 3.369, 3.448, 3.406 and 3.466 Å.
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spelling pubmed-29602932010-12-30 Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II) Bagchi, Vivek Bandyopadhyay, Debkumar Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pt(C(13)H(10)ClN(2)S)Cl], contains a Pt atom tetra­coordinated by a benzene C, a diazene N, a Cl and an S atom in an approximately square-planar geometry. The mol­ecules dimerize through a nonbonded S⋯S inter­action [S⋯S = 3.523 (18) Å]. There are no hydrogen bonds and the crystal packing is stabilized by four inter­molecular π–π inter­actions; the centroid–centroid distances are 3.804 (3), 3.638 (3), 3.804 (3) and 3.638 (3) Å, and the corresponding perpendicular distances are 3.369, 3.448, 3.406 and 3.466 Å. International Union of Crystallography 2008-01-16 /pmc/articles/PMC2960293/ /pubmed/21201318 http://dx.doi.org/10.1107/S1600536808000767 Text en © Bagchi and Bandyopadhyay 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bagchi, Vivek
Bandyopadhyay, Debkumar
Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)
title Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)
title_full Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)
title_fullStr Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)
title_full_unstemmed Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)
title_short Chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(II)
title_sort chlorido{5-chloro-2-[2-(methyl­sulfanyl)phenyl­diazen­yl]phenyl}­platinum(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960293/
https://www.ncbi.nlm.nih.gov/pubmed/21201318
http://dx.doi.org/10.1107/S1600536808000767
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AT bandyopadhyaydebkumar chlorido5chloro22methylsulfanylphenyldiazenylphenylplatinumii

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