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Tetra-μ-benzoato-bis[(quinoxaline)copper(II)]
The paddlewheel-type centrosymmetric dinuclear title complex, [Cu(2)(C(7)H(5)O(2))(4)(C(8)H(6)N(2))(2)], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octahedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
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International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960297/ https://www.ncbi.nlm.nih.gov/pubmed/21201265 http://dx.doi.org/10.1107/S1600536807067876 |
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author | Lee, Eun Yong Park, Byeong Kwon Kim, Cheal Kim, Sung-Jin Kim, Youngmee |
author_facet | Lee, Eun Yong Park, Byeong Kwon Kim, Cheal Kim, Sung-Jin Kim, Youngmee |
author_sort | Lee, Eun Yong |
collection | PubMed |
description | The paddlewheel-type centrosymmetric dinuclear title complex, [Cu(2)(C(7)H(5)O(2))(4)(C(8)H(6)N(2))(2)], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octahedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline molecule [Cu—N = 2.2465 (18) Å] and by the second Cu atom [Cu⋯Cu = 2.668 (5) Å]. The Cu atom is 0.216 Å out of the plane of the four O atoms. |
format | Text |
id | pubmed-2960297 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29602972010-12-30 Tetra-μ-benzoato-bis[(quinoxaline)copper(II)] Lee, Eun Yong Park, Byeong Kwon Kim, Cheal Kim, Sung-Jin Kim, Youngmee Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The paddlewheel-type centrosymmetric dinuclear title complex, [Cu(2)(C(7)H(5)O(2))(4)(C(8)H(6)N(2))(2)], contains four bridging benzoate groups and two terminal quinoxaline ligands. The octahedral coordination around each Cu atom, with four O atoms in the equatorial plane, is completed by an N atom of a quinoxaline molecule [Cu—N = 2.2465 (18) Å] and by the second Cu atom [Cu⋯Cu = 2.668 (5) Å]. The Cu atom is 0.216 Å out of the plane of the four O atoms. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960297/ /pubmed/21201265 http://dx.doi.org/10.1107/S1600536807067876 Text en © Lee et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Lee, Eun Yong Park, Byeong Kwon Kim, Cheal Kim, Sung-Jin Kim, Youngmee Tetra-μ-benzoato-bis[(quinoxaline)copper(II)] |
title | Tetra-μ-benzoato-bis[(quinoxaline)copper(II)] |
title_full | Tetra-μ-benzoato-bis[(quinoxaline)copper(II)] |
title_fullStr | Tetra-μ-benzoato-bis[(quinoxaline)copper(II)] |
title_full_unstemmed | Tetra-μ-benzoato-bis[(quinoxaline)copper(II)] |
title_short | Tetra-μ-benzoato-bis[(quinoxaline)copper(II)] |
title_sort | tetra-μ-benzoato-bis[(quinoxaline)copper(ii)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960297/ https://www.ncbi.nlm.nih.gov/pubmed/21201265 http://dx.doi.org/10.1107/S1600536807067876 |
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