N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea

In the title compound, C(20)H(17)N(3)OS, the dihedral angle between the benzene rings of the biphenyl fragment is 36.84 (9)°. The trans–cis geometry of the thio­urea unit is stabilized by intra­molecular N—H⋯O and N—H⋯N hydrogen bonds between the H atom of the cis thio­amide and the carbonyl O and p...

Descripción completa

Detalles Bibliográficos
Autores principales: Yamin, Bohari M., Deris, Hidayah, Malik, Zaw Myint, Yousuf, Sammer
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960299/
https://www.ncbi.nlm.nih.gov/pubmed/21201392
http://dx.doi.org/10.1107/S1600536807067499
_version_ 1782188706001584128
author Yamin, Bohari M.
Deris, Hidayah
Malik, Zaw Myint
Yousuf, Sammer
author_facet Yamin, Bohari M.
Deris, Hidayah
Malik, Zaw Myint
Yousuf, Sammer
author_sort Yamin, Bohari M.
collection PubMed
description In the title compound, C(20)H(17)N(3)OS, the dihedral angle between the benzene rings of the biphenyl fragment is 36.84 (9)°. The trans–cis geometry of the thio­urea unit is stabilized by intra­molecular N—H⋯O and N—H⋯N hydrogen bonds between the H atom of the cis thio­amide and the carbonyl O and pyridine N atoms, respectively. In the crystal structure, inter­molecular N—H⋯S hydrogen bonds form centrosymmetric dimers extending along the b axis.
format Text
id pubmed-2960299
institution National Center for Biotechnology Information
language English
publishDate 2008
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29602992010-12-30 N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea Yamin, Bohari M. Deris, Hidayah Malik, Zaw Myint Yousuf, Sammer Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(17)N(3)OS, the dihedral angle between the benzene rings of the biphenyl fragment is 36.84 (9)°. The trans–cis geometry of the thio­urea unit is stabilized by intra­molecular N—H⋯O and N—H⋯N hydrogen bonds between the H atom of the cis thio­amide and the carbonyl O and pyridine N atoms, respectively. In the crystal structure, inter­molecular N—H⋯S hydrogen bonds form centrosymmetric dimers extending along the b axis. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960299/ /pubmed/21201392 http://dx.doi.org/10.1107/S1600536807067499 Text en © Yamin et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamin, Bohari M.
Deris, Hidayah
Malik, Zaw Myint
Yousuf, Sammer
N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea
title N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea
title_full N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea
title_fullStr N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea
title_full_unstemmed N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea
title_short N-(Biphenyl-4-ylcarbon­yl)-N′-(2-pyridylmeth­yl)thio­urea
title_sort n-(biphenyl-4-ylcarbon­yl)-n′-(2-pyridylmeth­yl)thio­urea
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960299/
https://www.ncbi.nlm.nih.gov/pubmed/21201392
http://dx.doi.org/10.1107/S1600536807067499
work_keys_str_mv AT yaminboharim nbiphenyl4ylcarbonyln2pyridylmethylthiourea
AT derishidayah nbiphenyl4ylcarbonyln2pyridylmethylthiourea
AT malikzawmyint nbiphenyl4ylcarbonyln2pyridylmethylthiourea
AT yousufsammer nbiphenyl4ylcarbonyln2pyridylmethylthiourea

Ejemplares similares