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Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)

In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol­ate S atom; the coordination geometry is distorted octa­hedral, with the two ligands in the mer configuration (two S atoms and two...

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Detalles Bibliográficos
Autores principales: Zhou, Xiu-Xia, Zhou, Zheng-Yuan, Chen, Jian-Qiao, Lin, Xiao-Ming, Cai, Yue-Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960303/
https://www.ncbi.nlm.nih.gov/pubmed/21201296
http://dx.doi.org/10.1107/S1600536807068493
Descripción
Sumario:In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol­ate S atom; the coordination geometry is distorted octa­hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol­ecules are linked by C—H⋯S hydrogen bonds, forming a three-dimensional network structure.