Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)

In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol­ate S atom; the coordination geometry is distorted octa­hedral, with the two ligands in the mer configuration (two S atoms and two...

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Autores principales: Zhou, Xiu-Xia, Zhou, Zheng-Yuan, Chen, Jian-Qiao, Lin, Xiao-Ming, Cai, Yue-Peng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960303/
https://www.ncbi.nlm.nih.gov/pubmed/21201296
http://dx.doi.org/10.1107/S1600536807068493
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author Zhou, Xiu-Xia
Zhou, Zheng-Yuan
Chen, Jian-Qiao
Lin, Xiao-Ming
Cai, Yue-Peng
author_facet Zhou, Xiu-Xia
Zhou, Zheng-Yuan
Chen, Jian-Qiao
Lin, Xiao-Ming
Cai, Yue-Peng
author_sort Zhou, Xiu-Xia
collection PubMed
description In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol­ate S atom; the coordination geometry is distorted octa­hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol­ecules are linked by C—H⋯S hydrogen bonds, forming a three-dimensional network structure.
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spelling pubmed-29603032010-12-30 Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II) Zhou, Xiu-Xia Zhou, Zheng-Yuan Chen, Jian-Qiao Lin, Xiao-Ming Cai, Yue-Peng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(8)H(8)N(3)S(2))(2)], the Zn atom is coordinated by the two ligands in a tridentate manner, via the pyridyl N, the azomethine N and the thiol­ate S atom; the coordination geometry is distorted octa­hedral, with the two ligands in the mer configuration (two S atoms and two pyridyl N atoms are cis with respect to each other and the azomethine N atoms is trans). The mol­ecules are linked by C—H⋯S hydrogen bonds, forming a three-dimensional network structure. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960303/ /pubmed/21201296 http://dx.doi.org/10.1107/S1600536807068493 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Metal-Organic Papers
Zhou, Xiu-Xia
Zhou, Zheng-Yuan
Chen, Jian-Qiao
Lin, Xiao-Ming
Cai, Yue-Peng
Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)
title Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)
title_full Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)
title_fullStr Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)
title_full_unstemmed Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)
title_short Bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(II)
title_sort bis[methyl 2-(2-pyridylmethyl­idene)hydrazinecarbodithio­ato]zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960303/
https://www.ncbi.nlm.nih.gov/pubmed/21201296
http://dx.doi.org/10.1107/S1600536807068493
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