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Aqua(3-formyl-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) methanol solvate
In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·CH(4)O, the Cu(II) ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal pla...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960304/ https://www.ncbi.nlm.nih.gov/pubmed/21201271 http://dx.doi.org/10.1107/S1600536807067967 |
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author | Zhang, Wu Cui, Qingxia Chang, Ling Yu, Zhaowen |
author_facet | Zhang, Wu Cui, Qingxia Chang, Ling Yu, Zhaowen |
author_sort | Zhang, Wu |
collection | PubMed |
description | In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·CH(4)O, the Cu(II) ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O—H⋯O hydrogen bonding. |
format | Text |
id | pubmed-2960304 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29603042010-12-30 Aqua(3-formyl-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) methanol solvate Zhang, Wu Cui, Qingxia Chang, Ling Yu, Zhaowen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the structure of the title complex, [Cu(C(8)H(4)O(4))(C(12)H(8)N(2))(H(2)O)]·CH(4)O, the Cu(II) ion is pentacoordinated in a tetragonal–pyramidal geometry, with two O atoms of the 3-formyl-2-oxidobenzoate (3-formylsalicylate) anion and two N atoms of 1,10-phenanthroline occupying the basal plane, and a water O atom located at the apical site. The structure displays O—H⋯O hydrogen bonding. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960304/ /pubmed/21201271 http://dx.doi.org/10.1107/S1600536807067967 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html. |
spellingShingle | Metal-Organic Papers Zhang, Wu Cui, Qingxia Chang, Ling Yu, Zhaowen Aqua(3-formyl-2-oxidobenzoato-κ(2) O (1),O (2))(1,10-phenanthroline-κ(2) N,N′)copper(II) methanol solvate |
title | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) methanol solvate |
title_full | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) methanol solvate |
title_fullStr | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) methanol solvate |
title_full_unstemmed | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) methanol solvate |
title_short | Aqua(3-formyl-2-oxidobenzoato-κ(2)
O
(1),O
(2))(1,10-phenanthroline-κ(2)
N,N′)copper(II) methanol solvate |
title_sort | aqua(3-formyl-2-oxidobenzoato-κ(2)
o
(1),o
(2))(1,10-phenanthroline-κ(2)
n,n′)copper(ii) methanol solvate |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960304/ https://www.ncbi.nlm.nih.gov/pubmed/21201271 http://dx.doi.org/10.1107/S1600536807067967 |
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