Aqua­chloridobis(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride N,N-dimethyl­formamide solvate

The Zn atom in the title salt, [ZnCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·C(3)H(7)NO, is chelated by two phenanthroline mol­ecules and is bonded to one chloride ion and one water mol­ecule, resulting in a ZnN(4)ClO octa­hedral coordination environment with the Cl and O atoms in a cis conformation. The cation...

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Detalles Bibliográficos
Autores principales: Kong, Li-Li, Gao, Shan, Huo, Li-Hua, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960305/
https://www.ncbi.nlm.nih.gov/pubmed/21201367
http://dx.doi.org/10.1107/S1600536808002237
Descripción
Sumario:The Zn atom in the title salt, [ZnCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·C(3)H(7)NO, is chelated by two phenanthroline mol­ecules and is bonded to one chloride ion and one water mol­ecule, resulting in a ZnN(4)ClO octa­hedral coordination environment with the Cl and O atoms in a cis conformation. The cations and anions are linked by O—H⋯Cl hydrogen bonds across a center of inversion, forming a hydrogen-bonded dimeric association. The dimethyl­formamide solvent mol­ecule is disordered over two orientations in a 0.56 (1):0.44 (1) ratio.

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