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Aquachloridobis(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride N,N-dimethylformamide solvate
The Zn atom in the title salt, [ZnCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·C(3)H(7)NO, is chelated by two phenanthroline molecules and is bonded to one chloride ion and one water molecule, resulting in a ZnN(4)ClO octahedral coordination environment with the Cl and O atoms in a cis conformation. The cation...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
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International Union of Crystallography
2008
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960305/ https://www.ncbi.nlm.nih.gov/pubmed/21201367 http://dx.doi.org/10.1107/S1600536808002237 |
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| author | Kong, Li-Li Gao, Shan Huo, Li-Hua Ng, Seik Weng |
| author_facet | Kong, Li-Li Gao, Shan Huo, Li-Hua Ng, Seik Weng |
| author_sort | Kong, Li-Li |
| collection | PubMed |
| description | The Zn atom in the title salt, [ZnCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·C(3)H(7)NO, is chelated by two phenanthroline molecules and is bonded to one chloride ion and one water molecule, resulting in a ZnN(4)ClO octahedral coordination environment with the Cl and O atoms in a cis conformation. The cations and anions are linked by O—H⋯Cl hydrogen bonds across a center of inversion, forming a hydrogen-bonded dimeric association. The dimethylformamide solvent molecule is disordered over two orientations in a 0.56 (1):0.44 (1) ratio. |
| format | Text |
| id | pubmed-2960305 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29603052010-12-30 Aquachloridobis(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride N,N-dimethylformamide solvate Kong, Li-Li Gao, Shan Huo, Li-Hua Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn atom in the title salt, [ZnCl(C(12)H(8)N(2))(2)(H(2)O)]Cl·C(3)H(7)NO, is chelated by two phenanthroline molecules and is bonded to one chloride ion and one water molecule, resulting in a ZnN(4)ClO octahedral coordination environment with the Cl and O atoms in a cis conformation. The cations and anions are linked by O—H⋯Cl hydrogen bonds across a center of inversion, forming a hydrogen-bonded dimeric association. The dimethylformamide solvent molecule is disordered over two orientations in a 0.56 (1):0.44 (1) ratio. International Union of Crystallography 2008-01-25 /pmc/articles/PMC2960305/ /pubmed/21201367 http://dx.doi.org/10.1107/S1600536808002237 Text en © Kong et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Kong, Li-Li Gao, Shan Huo, Li-Hua Ng, Seik Weng Aquachloridobis(1,10-phenanthroline-κ(2) N,N′)zinc(II) chloride N,N-dimethylformamide solvate |
| title | Aquachloridobis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) chloride N,N-dimethylformamide solvate |
| title_full | Aquachloridobis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) chloride N,N-dimethylformamide solvate |
| title_fullStr | Aquachloridobis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) chloride N,N-dimethylformamide solvate |
| title_full_unstemmed | Aquachloridobis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) chloride N,N-dimethylformamide solvate |
| title_short | Aquachloridobis(1,10-phenanthroline-κ(2)
N,N′)zinc(II) chloride N,N-dimethylformamide solvate |
| title_sort | aquachloridobis(1,10-phenanthroline-κ(2)
n,n′)zinc(ii) chloride n,n-dimethylformamide solvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960305/ https://www.ncbi.nlm.nih.gov/pubmed/21201367 http://dx.doi.org/10.1107/S1600536808002237 |
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