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(μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4) O (5),O (6):O (2),N (3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2) O (4),O (5))(1,10-phenanthroline-κ(2) N,N′)neodymium(III)] hexahydrate
The water-coordinated neodymium(III) atom in the centrosymmetric title compound, [Nd(2)(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)]·6H(2)O is chelated by a 1,10-phenanthroline heterocycle and two 2,4-dihydroxypyrimidine-5-carboxylate dianions. Two tris-chelated water-coordi...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960306/ https://www.ncbi.nlm.nih.gov/pubmed/21201364 http://dx.doi.org/10.1107/S1600536808001499 |
Sumario: | The water-coordinated neodymium(III) atom in the centrosymmetric title compound, [Nd(2)(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)]·6H(2)O is chelated by a 1,10-phenanthroline heterocycle and two 2,4-dihydroxypyrimidine-5-carboxylate dianions. Two tris-chelated water-coordinated units are bridged by a 2,4-dihydroxypyrimidine-5-carboxylate dianion, which is disordered about a center of inversion. The metal center has a monocapped square-antiprismatic coordination. |
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