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(μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4) O (5),O (6):O (2),N (3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2) O (4),O (5))(1,10-phenanthroline-κ(2) N,N′)neodymium(III)] hexahydrate
The water-coordinated neodymium(III) atom in the centrosymmetric title compound, [Nd(2)(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)]·6H(2)O is chelated by a 1,10-phenanthroline heterocycle and two 2,4-dihydroxypyrimidine-5-carboxylate dianions. Two tris-chelated water-coordi...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2008
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960306/ https://www.ncbi.nlm.nih.gov/pubmed/21201364 http://dx.doi.org/10.1107/S1600536808001499 |
| _version_ | 1782188707799891968 |
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| author | Xing, Hui-Hui Chen, Zi-Lu Ng, Seik Weng |
| author_facet | Xing, Hui-Hui Chen, Zi-Lu Ng, Seik Weng |
| author_sort | Xing, Hui-Hui |
| collection | PubMed |
| description | The water-coordinated neodymium(III) atom in the centrosymmetric title compound, [Nd(2)(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)]·6H(2)O is chelated by a 1,10-phenanthroline heterocycle and two 2,4-dihydroxypyrimidine-5-carboxylate dianions. Two tris-chelated water-coordinated units are bridged by a 2,4-dihydroxypyrimidine-5-carboxylate dianion, which is disordered about a center of inversion. The metal center has a monocapped square-antiprismatic coordination. |
| format | Text |
| id | pubmed-2960306 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2008 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29603062010-12-30 (μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4) O (5),O (6):O (2),N (3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2) O (4),O (5))(1,10-phenanthroline-κ(2) N,N′)neodymium(III)] hexahydrate Xing, Hui-Hui Chen, Zi-Lu Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The water-coordinated neodymium(III) atom in the centrosymmetric title compound, [Nd(2)(C(5)H(2)N(2)O(4))(C(5)H(3)N(2)O(4))(4)(C(12)H(8)N(2))(2)(H(2)O)(2)]·6H(2)O is chelated by a 1,10-phenanthroline heterocycle and two 2,4-dihydroxypyrimidine-5-carboxylate dianions. Two tris-chelated water-coordinated units are bridged by a 2,4-dihydroxypyrimidine-5-carboxylate dianion, which is disordered about a center of inversion. The metal center has a monocapped square-antiprismatic coordination. International Union of Crystallography 2008-01-25 /pmc/articles/PMC2960306/ /pubmed/21201364 http://dx.doi.org/10.1107/S1600536808001499 Text en © Xing et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Xing, Hui-Hui Chen, Zi-Lu Ng, Seik Weng (μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4) O (5),O (6):O (2),N (3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2) O (4),O (5))(1,10-phenanthroline-κ(2) N,N′)neodymium(III)] hexahydrate |
| title | (μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4)
O
(5),O
(6):O
(2),N
(3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2)
O
(4),O
(5))(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] hexahydrate |
| title_full | (μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4)
O
(5),O
(6):O
(2),N
(3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2)
O
(4),O
(5))(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] hexahydrate |
| title_fullStr | (μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4)
O
(5),O
(6):O
(2),N
(3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2)
O
(4),O
(5))(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] hexahydrate |
| title_full_unstemmed | (μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4)
O
(5),O
(6):O
(2),N
(3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2)
O
(4),O
(5))(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] hexahydrate |
| title_short | (μ-6-Oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4)
O
(5),O
(6):O
(2),N
(3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2)
O
(4),O
(5))(1,10-phenanthroline-κ(2)
N,N′)neodymium(III)] hexahydrate |
| title_sort | (μ-6-oxido-4-oxo-1,2-dihydropyrimidine-5-carboxylato-κ(4)
o
(5),o
(6):o
(2),n
(3))bis[aquabis(4-oxido-2-oxo-1,2-dihydropyrimidin-3-ium-5-carboxylato-κ(2)
o
(4),o
(5))(1,10-phenanthroline-κ(2)
n,n′)neodymium(iii)] hexahydrate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960306/ https://www.ncbi.nlm.nih.gov/pubmed/21201364 http://dx.doi.org/10.1107/S1600536808001499 |
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