Cargando…

catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]

The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol­ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinate...

Descripción completa

Detalles Bibliográficos
Autores principales: Padmanabhan, M., Joseph, James C., Olsson, Susanne, Bakir, Mohammed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960309/
https://www.ncbi.nlm.nih.gov/pubmed/21201278
http://dx.doi.org/10.1107/S1600536808000160
Descripción
Sumario:The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol­ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol­ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu—O distance [2.873 (3) Å] is to a water mol­ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa­hedral geometry of the [5+1] type. O—H⋯O and N—H⋯O hydrogen bonds are observed in the crystal structure.