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catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]

The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol­ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinate...

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Detalles Bibliográficos
Autores principales: Padmanabhan, M., Joseph, James C., Olsson, Susanne, Bakir, Mohammed
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960309/
https://www.ncbi.nlm.nih.gov/pubmed/21201278
http://dx.doi.org/10.1107/S1600536808000160
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author Padmanabhan, M.
Joseph, James C.
Olsson, Susanne
Bakir, Mohammed
author_facet Padmanabhan, M.
Joseph, James C.
Olsson, Susanne
Bakir, Mohammed
author_sort Padmanabhan, M.
collection PubMed
description The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol­ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol­ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu—O distance [2.873 (3) Å] is to a water mol­ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa­hedral geometry of the [5+1] type. O—H⋯O and N—H⋯O hydrogen bonds are observed in the crystal structure.
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spelling pubmed-29603092010-12-30 catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate] Padmanabhan, M. Joseph, James C. Olsson, Susanne Bakir, Mohammed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol­ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol­ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu—O distance [2.873 (3) Å] is to a water mol­ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa­hedral geometry of the [5+1] type. O—H⋯O and N—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960309/ /pubmed/21201278 http://dx.doi.org/10.1107/S1600536808000160 Text en © Padmanabhan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Padmanabhan, M.
Joseph, James C.
Olsson, Susanne
Bakir, Mohammed
catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]
title catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]
title_full catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]
title_fullStr catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]
title_full_unstemmed catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]
title_short catena-Poly[[[aqua­(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]
title_sort catena-poly[[[aqua­(propane-1,3-diamine-κ(2) n,n′)copper(ii)]-μ-fumarato-κ(2) o:o′] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960309/
https://www.ncbi.nlm.nih.gov/pubmed/21201278
http://dx.doi.org/10.1107/S1600536808000160
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