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catena-Poly[[[aqua(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate]
The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water molecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinate...
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2008
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960309/ https://www.ncbi.nlm.nih.gov/pubmed/21201278 http://dx.doi.org/10.1107/S1600536808000160 |
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author | Padmanabhan, M. Joseph, James C. Olsson, Susanne Bakir, Mohammed |
author_facet | Padmanabhan, M. Joseph, James C. Olsson, Susanne Bakir, Mohammed |
author_sort | Padmanabhan, M. |
collection | PubMed |
description | The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water molecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water molecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu—O distance [2.873 (3) Å] is to a water molecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octahedral geometry of the [5+1] type. O—H⋯O and N—H⋯O hydrogen bonds are observed in the crystal structure. |
format | Text |
id | pubmed-2960309 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2008 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29603092010-12-30 catena-Poly[[[aqua(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate] Padmanabhan, M. Joseph, James C. Olsson, Susanne Bakir, Mohammed Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water molecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water molecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu—O distance [2.873 (3) Å] is to a water molecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octahedral geometry of the [5+1] type. O—H⋯O and N—H⋯O hydrogen bonds are observed in the crystal structure. International Union of Crystallography 2008-01-09 /pmc/articles/PMC2960309/ /pubmed/21201278 http://dx.doi.org/10.1107/S1600536808000160 Text en © Padmanabhan et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Padmanabhan, M. Joseph, James C. Olsson, Susanne Bakir, Mohammed catena-Poly[[[aqua(propane-1,3-diamine-κ(2) N,N′)copper(II)]-μ-fumarato-κ(2) O:O′] monohydrate] |
title |
catena-Poly[[[aqua(propane-1,3-diamine-κ(2)
N,N′)copper(II)]-μ-fumarato-κ(2)
O:O′] monohydrate] |
title_full |
catena-Poly[[[aqua(propane-1,3-diamine-κ(2)
N,N′)copper(II)]-μ-fumarato-κ(2)
O:O′] monohydrate] |
title_fullStr |
catena-Poly[[[aqua(propane-1,3-diamine-κ(2)
N,N′)copper(II)]-μ-fumarato-κ(2)
O:O′] monohydrate] |
title_full_unstemmed |
catena-Poly[[[aqua(propane-1,3-diamine-κ(2)
N,N′)copper(II)]-μ-fumarato-κ(2)
O:O′] monohydrate] |
title_short |
catena-Poly[[[aqua(propane-1,3-diamine-κ(2)
N,N′)copper(II)]-μ-fumarato-κ(2)
O:O′] monohydrate] |
title_sort | catena-poly[[[aqua(propane-1,3-diamine-κ(2)
n,n′)copper(ii)]-μ-fumarato-κ(2)
o:o′] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960309/ https://www.ncbi.nlm.nih.gov/pubmed/21201278 http://dx.doi.org/10.1107/S1600536808000160 |
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