Poly[hexa­aqua­copper(II) [di-μ(3)-sulfato-disodiate(I)]]

The title compound, {[Cu(H(2)O)(6)][Na(2)(SO(4))(2)]}(n), has been prepared under mild hydro­thermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a spe...

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Detalles Bibliográficos
Autores principales: Wu, Wen, Xie, J.-M., Xie, D.-P., Xuan, Y.-W.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960320/
https://www.ncbi.nlm.nih.gov/pubmed/21201248
http://dx.doi.org/10.1107/S1600536807067608
Descripción
Sumario:The title compound, {[Cu(H(2)O)(6)][Na(2)(SO(4))(2)]}(n), has been prepared under mild hydro­thermal conditions and has been structurally characterized. It exhibits a structure in which the inorganic frameworks are three-dimensional, participating in extensive hydrogen bonding. Copper occupies a special position ([Image: see text]). The Na atom is coordinated by five O atoms of four sulfates [Na—O distances are between 2.825 (3) and 2.983 (3) Å]. The four O atoms of the sulfate ligand are coordinated to four Na atoms, the sulfate ligands coordinating in a chelating/bridging tetra­dentate mode.

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