Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)

The title cocrystal, C(18)H(15)OP·C(6)H(6)O(2), belongs to a series of mol­ecular systems based on triphenyl­phosphine P-oxide. The O atom of the oxide group acts as an acceptor for hydrogen bonds from OH groups of two hydro­quinone mol­ecules which lie on inversion centres [O⋯O = 2.7451 (17) and 2....

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Detalles Bibliográficos
Autores principales: Moreno-Fuquen, Rodolfo, Valderrama-N, Jaime, Shankland, Kenneth, Fabbiani, Francesa P. A., Markvardsen, Anders J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960326/
https://www.ncbi.nlm.nih.gov/pubmed/21201399
http://dx.doi.org/10.1107/S1600536807067414
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author Moreno-Fuquen, Rodolfo
Valderrama-N, Jaime
Shankland, Kenneth
Fabbiani, Francesa P. A.
Markvardsen, Anders J.
author_facet Moreno-Fuquen, Rodolfo
Valderrama-N, Jaime
Shankland, Kenneth
Fabbiani, Francesa P. A.
Markvardsen, Anders J.
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description The title cocrystal, C(18)H(15)OP·C(6)H(6)O(2), belongs to a series of mol­ecular systems based on triphenyl­phosphine P-oxide. The O atom of the oxide group acts as an acceptor for hydrogen bonds from OH groups of two hydro­quinone mol­ecules which lie on inversion centres [O⋯O = 2.7451 (17) and 2.681 (2) Å]. The crystal structure is stabilized by weak C—H⋯O hydrogen bonds, forming a C (2) (1)(8) chain which runs parallel to the [100] direction.
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spelling pubmed-29603262010-12-30 Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1) Moreno-Fuquen, Rodolfo Valderrama-N, Jaime Shankland, Kenneth Fabbiani, Francesa P. A. Markvardsen, Anders J. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title cocrystal, C(18)H(15)OP·C(6)H(6)O(2), belongs to a series of mol­ecular systems based on triphenyl­phosphine P-oxide. The O atom of the oxide group acts as an acceptor for hydrogen bonds from OH groups of two hydro­quinone mol­ecules which lie on inversion centres [O⋯O = 2.7451 (17) and 2.681 (2) Å]. The crystal structure is stabilized by weak C—H⋯O hydrogen bonds, forming a C (2) (1)(8) chain which runs parallel to the [100] direction. International Union of Crystallography 2008-01-04 /pmc/articles/PMC2960326/ /pubmed/21201399 http://dx.doi.org/10.1107/S1600536807067414 Text en © Moreno-Fuquen et al. 2008 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moreno-Fuquen, Rodolfo
Valderrama-N, Jaime
Shankland, Kenneth
Fabbiani, Francesa P. A.
Markvardsen, Anders J.
Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)
title Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)
title_full Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)
title_fullStr Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)
title_full_unstemmed Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)
title_short Three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)
title_sort three-centre hydrogen bonds in triphenyl­phosphine oxide–hydro­quinone (1/1)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960326/
https://www.ncbi.nlm.nih.gov/pubmed/21201399
http://dx.doi.org/10.1107/S1600536807067414
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