5-(1H-Inden-2-yl)-1,3-benzodioxole

In the title compound, C(16)H(12)O(2), the non-H atoms are coplanar with a mean r.m.s. deviation of 0.0260 (2) Å. The deviations of the bond angles from normal values at the indenyl junction C atom and the indenyl bridgehead C atom nearest the junction are imposed by the five-membered ring geometry....

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Detalles Bibliográficos
Autores principales: Deng, Rui-Xue, Zhou, Wei-Yi, Deng, Xiao-Juan, Sun, Liang-Dong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960328/
https://www.ncbi.nlm.nih.gov/pubmed/21201515
http://dx.doi.org/10.1107/S1600536808001578
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author Deng, Rui-Xue
Zhou, Wei-Yi
Deng, Xiao-Juan
Sun, Liang-Dong
author_facet Deng, Rui-Xue
Zhou, Wei-Yi
Deng, Xiao-Juan
Sun, Liang-Dong
author_sort Deng, Rui-Xue
collection PubMed
description In the title compound, C(16)H(12)O(2), the non-H atoms are coplanar with a mean r.m.s. deviation of 0.0260 (2) Å. The deviations of the bond angles from normal values at the indenyl junction C atom and the indenyl bridgehead C atom nearest the junction are imposed by the five-membered ring geometry. Due to conjugation, the single bond linking the two ring systems [1.455 (3) Å] is significantly shorter than the formal single bonds in the five-membered carbocyclic ring [1.500 (3) and 1.489 (3) Å].
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spelling pubmed-29603282010-12-30 5-(1H-Inden-2-yl)-1,3-benzodioxole Deng, Rui-Xue Zhou, Wei-Yi Deng, Xiao-Juan Sun, Liang-Dong Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(12)O(2), the non-H atoms are coplanar with a mean r.m.s. deviation of 0.0260 (2) Å. The deviations of the bond angles from normal values at the indenyl junction C atom and the indenyl bridgehead C atom nearest the junction are imposed by the five-membered ring geometry. Due to conjugation, the single bond linking the two ring systems [1.455 (3) Å] is significantly shorter than the formal single bonds in the five-membered carbocyclic ring [1.500 (3) and 1.489 (3) Å]. International Union of Crystallography 2008-01-23 /pmc/articles/PMC2960328/ /pubmed/21201515 http://dx.doi.org/10.1107/S1600536808001578 Text en © International Union of Crystallography 2008 http://journals.iucr.org/services/termsofuse.html This is an open-access article distributed under the terms described at http://journals.iucr.org/services/termsofuse.html.
spellingShingle Organic Papers
Deng, Rui-Xue
Zhou, Wei-Yi
Deng, Xiao-Juan
Sun, Liang-Dong
5-(1H-Inden-2-yl)-1,3-benzodioxole
title 5-(1H-Inden-2-yl)-1,3-benzodioxole
title_full 5-(1H-Inden-2-yl)-1,3-benzodioxole
title_fullStr 5-(1H-Inden-2-yl)-1,3-benzodioxole
title_full_unstemmed 5-(1H-Inden-2-yl)-1,3-benzodioxole
title_short 5-(1H-Inden-2-yl)-1,3-benzodioxole
title_sort 5-(1h-inden-2-yl)-1,3-benzodioxole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960328/
https://www.ncbi.nlm.nih.gov/pubmed/21201515
http://dx.doi.org/10.1107/S1600536808001578
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AT zhouweiyi 51hinden2yl13benzodioxole
AT dengxiaojuan 51hinden2yl13benzodioxole
AT sunliangdong 51hinden2yl13benzodioxole

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