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Redetermination at 113 K of 2,2-tetra­methyl­ene-1,2-dihydro­quinazolin-4(3H)-one

The title compound {systematic name: spiro­[cyclo­pentane-1,2′(1′H)-quinazolin]-4′(3′H)-one]}, C(12)H(14)N(2)O, has been reported previously [Klemm, Weakley, Gilbertson & Song (1998 ▶). J. Heterocycl Chem. 35, 1269–1273]. Its structure has been redetermined at 113 K with greater precision for al...

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Detalles Bibliográficos
Autores principales: Zhang, Lijun, Li, Jiarong, Shi, Daxin, Chen, Jinnan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2008
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2960329/
https://www.ncbi.nlm.nih.gov/pubmed/21201476
http://dx.doi.org/10.1107/S1600536807066706
Descripción
Sumario:The title compound {systematic name: spiro­[cyclo­pentane-1,2′(1′H)-quinazolin]-4′(3′H)-one]}, C(12)H(14)N(2)O, has been reported previously [Klemm, Weakley, Gilbertson & Song (1998 ▶). J. Heterocycl Chem. 35, 1269–1273]. Its structure has been redetermined at 113 K with greater precision for all data. The mol­ecule is built up from two fused six-membered rings and one five-membered ring linked through a spiro C atom. The pyrimidine ring has an envelope conformation and the cyclopentane ring adopts a distorted boat form. There are inter­molecular N—H⋯O hydrogen bonds, which form a two-dimensional sheet parallel to the (001) plane.